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Perkin Transactions 1 1972-2002 logo

Year 1975
Main Index

Issue 0


Errata

pg X001; DOI:
10.1039/P1975000X001
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Notices to authors

pg X002; DOI:
10.1039/P1975000X002
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Index of authors, 1975

pg 2533; DOI:
10.1039/P19750002533
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Index of subjects, 1975

pg 2557; DOI:
10.1039/P19750002557
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Issue 1


Contents pages

pg P001; DOI:
10.1039/P197500FP001
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Reactive intermediates. Part XXIV. 1H-Azirine intermediates in the pyrolysis of 1H-1,2,3-triazoles
Thomas L. Gilchrist Geoffrey E. Gymer and Charles W. Rees
pg 1; DOI:
10.1039/P19750000001
PDF
Reactive intermediates. Part XXV. Investigation of the pyrolysis of 1,4- and 1,5-diphenyl-1,2,3-triazoles by use of 13C-labelled compounds
Thomas L. Gilchrist Charles W. Rees and Colin Thomas
pg 8; DOI:
10.1039/P19750000008
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Reactive intermediates. Part XXVI. Flash vacuum pyrolysis of phenyl-substituted 1,2,4-triazoles; a new synthesis of isoindoles
Thomas L. Gilchrist Charles W. Rees and Colin Thomas
pg 12; DOI:
10.1039/P19750000012
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Benzo[c]cinnoline N-imides
Stephanie F. Gait Michael E. Peek Charles W. Rees and Richard S. Storr
pg 19; DOI:
10.1039/P19750000019
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Azimines as 1,3-dipoles
S. Richard Challand Stephanie F. Gait Michael J. Rance Charles W. Rees and Richard C. Storr
pg 26; DOI:
10.1039/P19750000026
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1,2,3-Benzotriazines
Brian M. Adger Steven Bradbury Martin Keating Charles W. Rees Richard C. Storr and Michael T. Williams
pg 31; DOI:
10.1039/P19750000031
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Attempted routes to benzazetes
Brian M. Adger Martin Keating Charles W. Rees and Richard C. Storr
pg 41; DOI:
10.1039/P19750000041
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Benzazetes (1-azabenzocyclobutenes)
Brian M. Adger Charles W. Rees and Richard C. Storr
pg 45; DOI:
10.1039/P19750000045
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The shikimate pathway. Part IV. The stereochemistry of the 3-dehydroquinate dehydratase reaction and observations on 3-dehydroquinate synthetase
Mervyn J. Turner Brian W. Smith and Edwin Haslam
pg 52; DOI:
10.1039/P19750000052
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Microbiological hydroxylation. Part XIV. Hydroxylation in the terminal rings of dioxygenated 5-androstanes with the fungi Wojnowicia graminis and Ophiobolus herpotrichus
(Mrs.) Virginia E. M. Chambers Sir Ewart R. H. Jones G. Denis Meakins John O. Miners and Alistair L. Wilkins
pg 55; DOI:
10.1039/P19750000055
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Isomerisation of 1,2,3,4,5,8-hexahydroisoquinolines to hexahydroisoquinolines containing a 1,3-diene system
Trevor A. Crabb and John R. Wilkinson
pg 58; DOI:
10.1039/P19750000058
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Reaction of lead tetra-acetate with aldehyde nitrophenylhydrazones
Richard N. Butler and William B. King
pg 61; DOI:
10.1039/P19750000061
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Selective nitration of aromatic substrates: reaction of nitrogen dioxide with arylthallium(III) compounds
(Mrs.) Beryl Davies and C. Barry Thomas
pg 65; DOI:
10.1039/P19750000065
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Autoxidation of polysubstituted isoindoles. Part II. Products from 1,3-diphenyl- and 1,2,3-triphenyl-isoindoles
Munir Ahmed Larry J. Kricka and John M. Vernon
pg 71; DOI:
10.1039/P19750000071
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Photocyclisation of some 1,6-diarylhexa-1,3,5-trienes
William Carruthers Nigel Evans and Ratnam Pooranamoorthy
pg 76; DOI:
10.1039/P19750000076
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Dehydration of some 9-methyl-9-hydroxybicyclo[3.3.1]nona-3,7-dien-2-ones
Choi-nang Lam and John M. Mellor
pg 80; DOI:
10.1039/P19750000080
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Partial synthesis of gibberellin A37 from gibberellin A13
David H. Bowen Christopher Cloke David M. Harrison and Jake MacMillan
pg 83; DOI:
10.1039/P19750000083
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Biosynthesis of terpenes and steroids. Part X. The sterols of some yeast mutants doubly defective in ergosterol biosynthesis
Derek H. R. Barton A. A. Leslie Gunatilaka Trevor R. Jarman David A. Widdowson Martin Bard and Robin A. Woods
pg 88; DOI:
10.1039/P19750000088
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Issue 2


Contents pages

pg P005; DOI:
10.1039/P197500FP005
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Photoaddition of the charge-transfer complexes of 7,7,8,8-tetracyanoquinodimethane–toluene systems
Kazuyuki Yamasaki Teijiro Yonezawa and Mamoru Ohashi
pg 93; DOI:
10.1039/P19750000093
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Some aspects of the oxidation of deoxyhumulones to humulones
Edward Collins Gareth D. John and Patrick V. R. Shannon
pg 96; DOI:
10.1039/P19750000096
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Steric effects in the reactions of -unsaturated ketonep-tolylsulphonylhydrazones: a route to 1,2-benzodiazepines via 1,7-ring closure of 1,1-diaryl-3-diazoalkenes
John T. Sharp Robert H. Findlay and Peter B. Thorogood
pg 102; DOI:
10.1039/P19750000102
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Stable carbocations. Part VIII. Fragmentation reactions of ferrocenylalkylium ions
Trevor S. Abram and William E. Watts
pg 113; DOI:
10.1039/P19750000113
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Stable carbocations. Part IX. Reactions involving sterically crowded ferrocenylalkylium ions
Trevor S. Abram and William E. Watts
pg 116; DOI:
10.1039/P19750000116
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Reactions of palladium(II) with organic compounds. Part III. Reactions of aromatic iodides in basic media
Ferrers R. S. Clark Richard O. C. Norman and C. Barry Thomas
pg 121; DOI:
10.1039/P19750000121
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A general synthesis of 4-substituted 1-(-D-ribofuranosyl)imidazo[4,5-c]pyridines
Jesse A. May jun. and Leroy B. Townsend
pg 125; DOI:
10.1039/P19750000125
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The chemistry of organoborates. Part I. New, high yield ketone syntheses by reaction of trialkylcyanoborates with acylating agents or N-phenylbenzimidoyl chloride
Andrew Pelter Keith Smith Michael G. Hutchings and Keith Rowe
pg 129; DOI:
10.1039/P19750000129
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The chemistry of organoborates. Part II. High yield syntheses of trialkylmethanols by the cyanoborate process
Andrew Pelter Michael G. Hutchings Keith Rowe and Keith Smith
pg 138; DOI:
10.1039/P19750000138
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The chemistry of organoborates. Part III. Protonation of trialkylcyanoborates
Andrew Pelter Michael G. Hutchings and Keith Smith
pg 142; DOI:
10.1039/P19750000142
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Chemistry of organoborates. Part IV. Stereochemistry and relative migratory aptitudes of alkyl groups in the cyanoborate process
Andrew Pelter Michael G. Hutchings Keith Smith and David J. Williams
pg 145; DOI:
10.1039/P19750000145
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Synthesis and reactions of isoprenyl terminal epoxides in the chromone and quinoline series
Michael F. Grundon and H. Martyn Okely
pg 150; DOI:
10.1039/P19750000150
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Cleavage of halogenobenzophenones by potassamide in ammonia; new routes to xanthen- and thioxanthen-9-ones
Martin S. Gibson S. Martin Vines and John M. Walthew
pg 155; DOI:
10.1039/P19750000155
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Reaction of phenyl-lithium and bromobenzene with carbon disulphide
Masataka Yokoyama Takeshi Kondo Nobuko Miyase and Masako Torri
pg 160; DOI:
10.1039/P19750000160
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Fungal products. Part XIII. Xanthomegnin, viomellin, rubrosulphin, and viopurpurin, pigments from Aspergillus sulphureus and Aspergillus melleus
Richard C. Durley Jake MacMillan Thomas J. Simpson Alasdair T. Glen and W. Brian Turner
pg 163; DOI:
10.1039/P19750000163
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A simple method for the removal of phenolic hydroxy-groups
Werner Lonsky Helmut Traitler and Karl Kratzl
pg 169; DOI:
10.1039/P19750000169
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o-Quinonoid compounds. Part VIII. Photodecarbonylation of 1,3-diphenylinden-2-one adducts; 1,5-sigmatropic shifts in sterically stabilised o-quinodimethanes
David W. Jones and Geoffrey Kneen
pg 171; DOI:
10.1039/P19750000171
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o-Quinonoid compounds. Part IX. Photodecarboxylation of 2-benzopyran-3-one adducts and photoreactions of the derived o-quinodimethanes
David W. Jones and Geoffrey Kneen
pg 175; DOI:
10.1039/P19750000175
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Studies on the synthesis of novel carbohydrates with sulphur in the ring. Part II. Analogues of derivatives of unsaturated deoxy-ulopyranosidonic acids via Diels–Alder reactions with methyl cyanodithioformate
Dolatrai M. Vyas and George W. Hay
pg 180; DOI:
10.1039/P19750000180
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Structures of the red sandalwood pigments santalins A and B
Alberto Arnone Lorenzo Camarda Lucio Merlini and Gianluca Nasini
pg 186; DOI:
10.1039/P19750000186
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Oxymetallation. Part VII. Peroxymercuration of terminal, medial, and cyclic alkenes without accompanying acyloxymercuration
A. J. Bloodworth and I. M. Griffin
pg 195; DOI:
10.1039/P19750000195
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Issue 3


Contents pages

pg P007; DOI:
10.1039/P197500FP007
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Mechanism of the reaction between trialkyl phosphates and dialkyl phosphorochloridates: nucleophilic sites in phosphorus(V) esters
Peter Simpson and Andrzej Zwierzak
pg 201; DOI:
10.1039/P19750000201
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Structures of two dimers formed from oroselol with acids
Vinayak S. Kamat Thakur D. Audichya Girish K. Trivedi and Sasanka C. Bhattacharyya
pg 204; DOI:
10.1039/P19750000204
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Reactions involving transition metals. Part VIII. Decomposition of hydroperoxides catalysed by iridium(I) and by rhodium(I) complexes
Brian L. Booth Robert N. Haszeldine and Geoffrey R. H. Neuss
pg 209; DOI:
10.1039/P19750000209
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N-bridged heterocycles. Part I. Synthesis and chemistry of NN-polymethylene-o-phenylenediamines
Roger J. Hayward and Otto Meth-Cohn
pg 212; DOI:
10.1039/P19750000212
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N-bridged heterocycles. Part II. Synthesis and aromaticity of 1,3-polymethylene-benzimidazolium salts {[n](1,3)benzimidazolophanium salts}, -benzimidazolones, and -benzimidazolethiones
Roger J. Hayward and Otto Meth-Cohn
pg 219; DOI:
10.1039/P19750000219
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Photo-oxidation of bilirubin in hydroxylic solvents
Raymond Bonnett and John Charles Marshall Stewart
pg 224; DOI:
10.1039/P19750000224
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Oxidation of oct-1-ene and trans-oct-4-ene by lead(IV), thallium(III), and mercury(II) acetates
Andrew Lethbridge Richard O. C. Norman C. Barry Thomas and William J. E. Parr
pg 231; DOI:
10.1039/P19750000231
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Extractives from Guttiferae. Part XXIX. Synthesis of celebixanthone methyl ether and related 1,5,6,7-tetraoxygenated xanthones
Augustus J. Quillinan and Feodor Scheinmann
pg 241; DOI:
10.1039/P19750000241
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Synthesis of ten isomers of a macrocyclic polyether, tetramethyldibenzo-18-crown-6, and their complexes with salts of alkali metals
David G. Parsons
pg 245; DOI:
10.1039/P19750000245
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A new regiospecific synthesis of 8-bromocamphor
Charles R. Eck Roy W. Mills and Thomas Money
pg 251; DOI:
10.1039/P19750000251
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Structure and transformation of products of the reactions of 2,2-thiodi-isobutyrophenone with hydrazine
Eric Cuthbertson Andrew D. U. Hardy and David D. MacNicol
pg 254; DOI:
10.1039/P19750000254
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Cyclisation reactions. Part III. Cyclisation of trans-2,3-epoxy-9-m-methoxyphenyl-2,6-dimethylnon-6-ene
Dhanonjoy Nasipuri and Swadesh R. Ray Chaudhuri
pg 262; DOI:
10.1039/P19750000262
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Potentially carcinogenic cyclopenta[a]phenanthrenes. Part X. Oxygenated derivatives of the carcinogen 15,16-dihydro-11-methylcyclopenta[a]phenanthren-17-one of metabolic interest
Maurice M. Coombs Maureen Hall Veronica A. Siddle and Colin W. Vose
pg 265; DOI:
10.1039/P19750000265
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Photochemical reactions of 1,2,4-dithiazole-3-thione and 1,2-dithiole-3-thione with olefins
Renji Okazaki Fumio Ishii Kazumi Okawa Kenji Ozawa and Naoki Inamoto
pg 270; DOI:
10.1039/P19750000270
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Studies in azole chemistry. Part I. Syntheses and reactions of some imidazole 3-oxides
Ian J. Ferguson and Kenneth Schofield
pg 275; DOI:
10.1039/P19750000275
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Neighbouring hydroxy-group participation in the reductive elimination of chlorine from 5,6-dichlorocholestanes with sodium borohydride
Yoram Houminer
pg 277; DOI:
10.1039/P19750000277
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Acyloxyoxosulphonium intermediates in the formation of sulphones from sulphoxides
Rita Annunziata Mauro Cinquini and Stefano Colonna
pg 282; DOI:
10.1039/P19750000282
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Nucleophile-induced cyclisation of 2-diazo-2-thiocyanatoacetophenone: 2-(cyanohydrazono)- and 2-(triphenylphosphoranylidenehydrazono)benzo[b]thiophen-3(2H)-one
William T. Flowers Geoffrey Holt Michael A. Hope and Constantine P. Poulos
pg 286; DOI:
10.1039/P19750000286
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An improved synthesis of 6H-pyrido[4,3-b]carbazole derivatives
Malcolm Sainsbury Brian Webb and Raymond Schinazi
pg 289; DOI:
10.1039/P19750000289
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Photochemical reactions of -aminovinyl phenyl ketones and related compounds
Hiromu Aoyama Takehiko Nishio Yoshitaka Hirabayashi Tadashi Hasegawa Hiroshi Noda and Noboru Sugiyama
pg 298; DOI:
10.1039/P19750000298
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Biosynthesis of aromatic isoprenoids. Part III. Mechanism of formation of the furan ring and origin of the 4-methoxy-group in the biosynthesis of furoquinoline alkaloids
Michael F. Grundon David M. Harrison and (Mrs.) Caroline G. Spyropoulos
pg 302; DOI:
10.1039/P19750000302
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N-quaternary compounds. Part XL. Syntheses of 1a,6a-dihydroindeno[1,2-b]azirin-6(1H)-ones and isomerisation to isoquinolinium derivatives
Per Egil Hansen and Kjell Undheim
pg 305; DOI:
10.1039/P19750000305
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Issue 4


Contents pages

pg P009; DOI:
10.1039/P197500FP009
PDF
Thiele–winter acetoxylation of quinones. Part VI. Methoxy- and hydroxy-(phenyl)-1,4-benzoquinones and (4-substituted phenyl)-1,4-benzoquinones
John M. Blatchly Richard J. S. Green John F. W. McOmie and Sadiq A. Saleh
pg 309; DOI:
10.1039/P19750000309
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Thiele–winter acetoxylation of quinones. Part VII. Some bromoderivatives of phenyl-1,4-benzoquinone
John F. W. McOmie John B. Searle and Sadiq A. Saleh
pg 314; DOI:
10.1039/P19750000314
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Photoaddition of allenes to p-quinones
Nobuyuki Ishibe Kiyoyasu Hashimoto and Yukio Yamaguchi
pg 318; DOI:
10.1039/P19750000318
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Epoxidation of 3,5-cyclo-5-androst-6-en-17-one
Richard C. Cambie Peter W. Thomas and James R. Hanson
pg 323; DOI:
10.1039/P19750000323
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Benzoquinone derivatives. Part I. Reactions of primary aliphatic amines with embelin (2,5-dihydroxy-3-undecyl-1,4-benzoquinone) and di-o-methylembelin
Balawant S. Joshi and Venkatesh N. Kamat
pg 327; DOI:
10.1039/P19750000327
PDF
The chemistry of terpenes. Part XVIII. Synthesis of methyl (–)-cis-chrysanthemate and of a methyl (+)-cis-homochrysanthemate from (+)-car-3- and -2-ene
Wesley Cocker Huntley St. J. Lauder and Patrick V. R. Shannon
pg 332; DOI:
10.1039/P19750000332
PDF
18-Norandrosta-8,11,13-trienes. Part IV. 7-Hydroxy-derivatives
Colin L. Hewett Samuel G. Gibson Iain M. Gilbert James Redpath David S. Savage Thomas Sleigh and Robert Taylor
pg 336; DOI:
10.1039/P19750000336
PDF
Acid-catalysed cyclisations of cyclo-octenylidene derivatives to produce bicyclo[3.3.1]nonanes
Robert S. Atkinson and Richard H. Green
pg 340; DOI:
10.1039/P19750000340
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v-Triazolo[4,5-d]pyrimidines (8-azapurines). Part XVI. Preparation of 6-amino-8-azapurines by heating 4-amino-1,2,3-triazole-5-carbonitrile (and its N-alkyl derivatives) with amidines
Adrien Albert
pg 345; DOI:
10.1039/P19750000345
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4-Acetyl-3-benzylidenepiperazine-2,5-diones
Srinivasachari Rajappa and Bhagwan G. Advani
pg 349; DOI:
10.1039/P19750000349
PDF
Constituents of the higher fungi Part XV. 3-(3,4-Dihydroxyphenyl)-2,7,8-trihydroxydibenzofuran-1,4-dione, a precursor of thelephoric acid from the fungus Suillus grevillei(klotsch) sing. [Boletus elegans(schum. per Fries)]
Raymond L. Edwards and Melvyn Gill
pg 351; DOI:
10.1039/P19750000351
PDF
Crustacean surface waxes. Part I. The hydrocarbons from the surface of Ligia oceanica
R. J. Hamilton M. Y. Raie I. Weatherston C. J. Brooks and Juliet H. Borthwick
pg 354; DOI:
10.1039/P19750000354
PDF
Microbiological hydroxylation. Part XV. Hydroxylation in the terminal rings of mono- and di-oxygenated 5-androstanes with the fungus Daedalea rufescens
Alan M. Bell Sir Ewart R. H. Jones G. Denis Meakins John O. Miners and Anthony Pendlebury
pg 357; DOI:
10.1039/P19750000357
PDF
The allyl ether as a protecting group in carbohydrate chemistry. Part VII. The 2-O-allyl group as a non-participant in 1,2-cis-glycoside synthesis
Patricia A. Gent and Roy Gigg
pg 361; DOI:
10.1039/P19750000361
PDF
Synthesis of 1,2-di-O-hexadecanoyl-3-O-(-D-galactopyranosyl)-L-glycerol (a galactosyl diglyceride) and 1,2-di-O-octadecanoyl-3-O-(6-O-octadecanoyl--D-galactopyranosyl)-L-glycerol
Patricia A. Gent and Roy Gigg
pg 364; DOI:
10.1039/P19750000364
PDF
Kinetics and mechanism of reaction of hydroxylamine with cytosine and its derivatives
G. Michael Blackburn Steven Jarvis Melvin C. Ryder and Vishnu Solan
pg 370; DOI:
10.1039/P19750000370
PDF
Condensation reactions of chloroformylsulphur chloride with 2- and 4-aminopyrimidines, 2-aminothiazole, and 2-amino-2-thiazoline
Derek Baldwin and Peter van den Broek
pg 375; DOI:
10.1039/P19750000375
PDF
Terpenoids. Part VI. Preparation of ent-[13,14-2H2]kaur-16-ene and some derivatives; bridgehead enolisation of ent-17-nor[13,14-2H2]kauran-16-one
David H. Bowen Christopher Cloke and Jake MacMillan
pg 378; DOI:
10.1039/P19750000378
PDF
Stereospecific exchange of a -methylene proton in phenylalanine preceding biosynthetic incorporation into gliotoxin
Nicholas Johns Gordon W. Kirby John D. Bu'Lock and Alan P. Ryles
pg 383; DOI:
10.1039/P19750000383
PDF
Degradation of cobaloximes to derivatives of imidazo[1,2-a]pyridine
Nathaniel W. Alcock Bernard T. Golding David R. Hall Ulrich Horn and William P. Watson
pg 386; DOI:
10.1039/P19750000386
PDF
Addition reactions of heterocyclic compounds. Part LIX. A 13C tracer study of the mechanism of formation of azepines from 2-methyl-quinolines and dimethyl acetylenedicarboxylate
R. Morrin Acheson and Rowena F. Flowerday
pg 394; DOI:
10.1039/P19750000394
PDF
Photochemistry of halogenocarbon compounds. Part I. Rearrangement of pyridazines to pyrazines
Richard D. Chambers J. A. Hugh MacBride Jerzy R. Maslakiewicz and Krishna C. Srivastava
pg 396; DOI:
10.1039/P19750000396
PDF

Issue 5


Contents pages

pg P011; DOI:
10.1039/P197500FP011
PDF
Synthesis of quinoxalinones by the reaction of o-phenylenediamines with dimethyl acetylenedicarboxylate
Hans Suschitzky Basil J. Wakefield and Roger A. Whittaker
pg 401; DOI:
10.1039/P19750000401
PDF
Mechanism and stereochemistry of nucleophilic substitutions in alkoxysulphonium salts. Part II. Competitive attack at sulphur and carbon in the reaction of alkoxydiarylsulphonium salts with halide ions
Rita Annunziata Mauro Cinquini and Stefano Colonna
pg 404; DOI:
10.1039/P19750000404
PDF
Effects of 3-substituents upon orientation in the 1,3-dipolar cyclo-addition reaction between 3-substituted pyridine N-imides and ethyl propiolate: syntheses of ethyl 4- and 6-substituted pyrazolo[1,5-a]-pyridine-3-carboxylates
Yasumitsu Tamura Yoshio Sumida Yasuyoshi Miki and Masazumi Ikeda
pg 406; DOI:
10.1039/P19750000406
PDF
Radical-induced cyclizations of cis-1,10-dichlorodec-5-ene and 1,10-dichlorodec-5-yne
Stuart A. Dodson and Robert D. Stipanovic
pg 410; DOI:
10.1039/P19750000410
PDF
Studies on the syntheses of heterocyclic compounds. Part DLXXXIX. A simple route to pyridocarbazoles
Tetsuji Kametani Toshio Suzuki Kimio Takahashi Yoshifumi Ichikawa and Keiichiro Fukumoto
pg 413; DOI:
10.1039/P19750000413
PDF
The biosynthesis of Lobelia alkaloids. Part III. Intermediates in the biosynthesis of lobeline; biosynthesis of 8,10-diethyl-lobelidione
Daniel G. O'Donovan Dermot J Long Edward Forde and Patrick Geary
pg 415; DOI:
10.1039/P19750000415
PDF
1H-benzo[de]cinnoline and 8-hydroxy-1-naphthonitrile
Philip H. Lacy and Donald C. C. Smith
pg 419; DOI:
10.1039/P19750000419
PDF
Reactions of dihydroquinolines and dihydroisoquinolines with arenesulphonyl azides
A. Sydney Bailey Trevor Morris and Zafar Rashid
pg 420; DOI:
10.1039/P19750000420
PDF
Natural acetylenes. Part XLVII. Biosynthetic experiments with the fungus Lepista diemii(singer). Biogenesis of the C8 acetylenic cyano-acid diatretyne 2
Sir Ewart R. H. Jones Viktor Thaller and John L. Turner
pg 424; DOI:
10.1039/P19750000424
PDF
An improved route to (3RS,5S)-[5-3H1]mevalonic acid
John Warcup Cornforth Frederick Patrick Ross and Claude Wakselman
pg 429; DOI:
10.1039/P19750000429
PDF
Studies related to penicillins. Part XV. Reactions of 2-oxa-4,7-diazabicyclo[3.2.0]hept-3-en-6-ones with thiols
David F. Corbett and Richard J. Stoodley
pg 432; DOI:
10.1039/P19750000432
PDF
Addition reactions of heterocyclic compounds. Part LVII. Reactions of pyridines with acetylenic esters in the presence of carbanion sources
R. Morrin Acheson and John Woollard
pg 438; DOI:
10.1039/P19750000438
PDF
Addition reactions of heterocyclic compounds. Part LVIII. Reactions of nitrogenous heterocycles with acetylacetylene
R. Morrin Acheson and John Woollard
pg 446; DOI:
10.1039/P19750000446
PDF
Crystalline chemical components of Fomes senex and structure of senexdiolic acid and related compounds
Ashok Kumar Batta and Srinivasa Rangaswami
pg 451; DOI:
10.1039/P19750000451
PDF
Rearrangements of 8-chloro-8-methylbicyclo[4.2.0]oct-2-en-7-one
William T. Brady and Patrick L. Ting
pg 456; DOI:
10.1039/P19750000456
PDF
Photochemical behaviour of some furo- and pyrrolo-[3,2-b]pyridin-2-ones
Gurnos Jones and John R. Phipps
pg 458; DOI:
10.1039/P19750000458
PDF
Steroids. Part X. A convenient synthesis of alkyl aryl ethers
Maghar S. Manhas W. H. Hoffman Bansi Lal and Ajay K. Bose
pg 461; DOI:
10.1039/P19750000461
PDF
A synthetic human insulin analogue modified at position B22. [Lys22-B] human insulin
Panayotis G. Katsoyannis James Ginos Alexandros Cosmatos and Gerald P. Schwartz
pg 464; DOI:
10.1039/P19750000464
PDF
Reduction of aryltrimethylsilanes as a synthetic method. Part II. Birch reduction
Colin Eaborn Richard A. Jackson and Ronald Pearce
pg 470; DOI:
10.1039/P19750000470
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Reduction of aryltrimethylsilanes as a synthetic method. Part III. Lithium in ethylamine (Benkeser reduction)
Colin Eaborn Richard A. Jackson and Ronald Pearce
pg 475; DOI:
10.1039/P19750000475
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Sesquiterpenoids. Part XLVII. Structure, configuration, conformation, and thermal rearrangement of furanodienone, isofuranodienone, curzerenone, epicurzerenone, and pyrocurzerenone, sesquiterpenoids of Curcuma zedoaria
Hiroshi Hikino Chohachi Konno Kunio Agatsuma Tsunematsu Takemoto Isao Horibe Kazuo Tori Masako Ueyama (nee Ohtsuru) and Ken'ichi Takeda
pg 478; DOI:
10.1039/P19750000478
PDF
Purine studies. Part XIV. Trifluoroacetyl and formyl derivatives of 4,5-diamino-6-methyl-2-methylthiopyrimidine, their ethylation products, and derived purines
M. David Fenn and John H. Lister
pg 485; DOI:
10.1039/P19750000485
PDF
Avicennol: a new pyranocoumarin from the root-bark of Zanthoxylum avicennae, and its conversion into avicennin
Alexander I. Gray Roger D. Waigh and Peter G. Waterman
pg 488; DOI:
10.1039/P19750000488
PDF
Tetranortriterpenoids and related substances. Part XVII. A new skeletal class of triterpenoids from Guarea glabra(Meliaceae)
George Ferguson P. Alastair Gunn Wayne C. Marsh Robert McCrindle Roderic Restivo Joseph D. Connolly John W. B. Fulke and Margaret S. Henderson
pg 491; DOI:
10.1039/P19750000491
PDF
Keten. Part XIII. Reactions of dimethylketen with some N-alkyl nitrones
R. Nigel Pratt David P. Stokes and Giles A. Taylor
pg 498; DOI:
10.1039/P19750000498
PDF
Pyrimidine derivatives and related compounds. Part XXVI. Oxidative and non-oxidative photocyclisations of 5-and 6-phenylthio- and anilino-1,3-dimethyluracils to benzothienopyrimidines and pyrimidoindoles
Shigeo Senda Kosaku Hirota and Mikio Takahashi
pg 503; DOI:
10.1039/P19750000503
PDF
Reactions between azolium anions and electrophilic reagents. Part II. Direct thiation of 1,2-disubstituted pyrazolium anions with sulphur
Mikael Begtrup
pg 507; DOI:
10.1039/P19750000507
PDF
Use of debenzylation of quaternary benzylammonium salts in the synthesis of -deuteriated tertiary amines
John R. Lindsay Smith John S. Sadd David H. Rosenblatt and George T. Davis
pg 510; DOI:
10.1039/P19750000510
PDF
Alkylphenylphosphinic amides: formation of stable, crystalline hydrochlorides, and hydrolysis in acidic solution
Martin J. P. Harger
pg 514; DOI:
10.1039/P19750000514
PDF
Intramolecular nitrene insertions into aromatic and heteroaromatic systems. Part III. Photochemical decomposition of azido-indanes and azido-1,2-dihydrobenzocyclobutenes
Robert N. Carde and Gurnos Jones
pg 519; DOI:
10.1039/P19750000519
PDF
Preparation of the fixed conformation esters 4,5-dihydrofuro- and 4,5-dihydrothieno-[2,3-c]pyran-7-one
Derek J. Chadwick John Chambers G. Denis Meakins and Roger L. Snowden
pg 523; DOI:
10.1039/P19750000523
PDF

Issue 6


Contents pages

pg P013; DOI:
10.1039/P197500FP013
PDF
Reaction of benzyne with carbon disulphide: formation and reaction of 1,3-benzodithiol-2-ylidene
Jyuzo Nakayama
pg 525; DOI:
10.1039/P19750000525
PDF
1,1-Diphenylalkenes. Part V. C-1 vs. C-3 alkylation of allylic carbanions; applicability of the principle of least motion
Richard Boyce Brendan A. Hayes William S. Murphy and Edward A. O'Riordan
pg 531; DOI:
10.1039/P19750000531
PDF
[1,4]Benzodioxinopyridazines
Donald E. Ames and Richard J. Ward
pg 534; DOI:
10.1039/P19750000534
PDF
Unsaturated nitrogen compounds containing fluorine. Part IV. Thermal reactions of hexafluoroacetone azine with hydrocarbon terminal olefins to give (1-pyrazolin-1-ylio)methanides or pyrazolines
Stuart E. Armstrong and Anthony E. Tipping
pg 538; DOI:
10.1039/P19750000538
PDF
The biosynthesis of fungal metabolites. Part V. Structure of variecoxanthones A, B, and C, metabolites of Aspergillus variecolor; conversion of variecoxanthone A into ()-de-C-prenylepishamixanthone
Kuldip K. Chexal John S. E. Holker Thomas J. Simpson and Kenneth Young
pg 543; DOI:
10.1039/P19750000543
PDF
The biosynthesis of fungal metabolites. Part VI. Structures and biosynthesis of some minor metabolites from variant strains of Aspergillus variecolor
Kuldip K. Chexal John S. E. Holker and Thomas J. Simpson
pg 549; DOI:
10.1039/P19750000549
PDF
The biosynthesis of fungal metabolites. Part VII. Production and biosynthesis of 4,7-dimethoxy-5-methylcoumarin in Aspergillus variecolor
Kuldip K. Chexal Christopher Fouweather and John S. E. Holker
pg 554; DOI:
10.1039/P19750000554
PDF
Extended dipolar cycloadditions
Stephanie F. Gait Michael J. Rance Charles W. Rees Reginald W. Stephenson and Richard C. Storr
pg 556; DOI:
10.1039/P19750000556
PDF
The chemistry of penicillanic acids. Part III. A route to 1,2-secopenicillins
Edward G. Brain Ian McMillan John H. C. Nayler Robert Southgate and Patricia Tolliday
pg 562; DOI:
10.1039/P19750000562
PDF
Reactions of quinones with aromatic ethers. Part V. Triphenylene-1,4-quinones from 2,3-diaryl-1,4-benzoquinones
Robert Buchan and Oliver C. Musgrave
pg 568; DOI:
10.1039/P19750000568
PDF
Decomposition products of pyrazolines formed from 3-alkylthioinden-1-ones and diazomethane
Katherine Buggle and Daniel O'Sullivan
pg 572; DOI:
10.1039/P19750000572
PDF
Synthesis of indolizines by intramolecular cyclisation of pyridinium allylides [1-(1-pyridinio)prop-2-enides]
Yasumitsu Tamura Yoshio Sumida Shin-Ichiro Haruki and Masazumi Ikeda
pg 575; DOI:
10.1039/P19750000575
PDF
Phenol oxidation and biosynthesis. Part XXV. New syntheses of bis-(2-arylethyl)amines of biosynthetic importance
Derek H. R. Barton Ruben D. Bracho A. A. Leslie Gunatilaka and David A. Widdowson
pg 579; DOI:
10.1039/P19750000579
PDF
Reduction of enaminones in the preparation of 3-aminocyclohexanols; a novel preparation of tetronic acid
John V. Greenhill Mohamed Ramli and Therezinha Tomassini
pg 588; DOI:
10.1039/P19750000588
PDF
A convenient synthesis of the tetra-aza-macrocyclic ligands trans-[14]-diene, tet a, and tet b
Robert W. Hay Geoffrey A. Lawrance and Niel F. Curtis
pg 591; DOI:
10.1039/P19750000591
PDF
Phosphorylated sugars. Part XV. Syntheses of 3-deoxy-D-erythro- and 3-deoxy-D-threo-hexulosonic acid 6-(dihydrogen phosphates)
François Trigalo Witold Jachymczyk John C. Young and Ladislas Szabó
pg 593; DOI:
10.1039/P19750000593
PDF
Phosphorylated sugars. Part XVI. Synthesis of 3-deoxy-D-glycero-hex-3-en-2-ulofuranos(2,5)onic acid 6-(dihydrogen phosphate)
François Trigalo and Ladislas Szabó
pg 598; DOI:
10.1039/P19750000598
PDF
Phosphorylated sugars. Part XVII. Synthesis of 3-deoxy-D-arabino-[1-14C]heptulosonic acid 7-(dihydrogen phosphate)
François Trigalo Michel Level and Ladislas Szabó
pg 600; DOI:
10.1039/P19750000600
PDF
Phosphorylated sugars. Part XVIII. Synthesis of D-glycero-D-gulo-heptose 4-(dihydrogen phosphate)
Annie Chiron and Patricia Szabó
pg 603; DOI:
10.1039/P19750000603
PDF
Phosphorylated sugars. Part XIX. Synthesis of 3-deoxy-D-glycero-pent-2-ulosonic acid 5-(dihydrogen phosphate)
François Trigalo and Ladislas Szabó
pg 604; DOI:
10.1039/P19750000604
PDF
Reactions of unsaturated 1,3-dioxan derivatives. Part VI. Addition of 2-(2-furyl)-1,3-dioxan and its derivatives to maleic anhydride
Jolanta Maliska-Solich
pg 606; DOI:
10.1039/P19750000606
PDF
Chemical investigation of ceylonese plants. Part XII. (+)-3,4,5,7-Tetrahydroxy-3-methoxyflavanone [(+)-dihydroisorhamnetin] and 3,5,7-trihydroxy-3,4-dimethoxyflavone (dillenetin): two new natural products from Dillenia indica L.
Gowsala Pavanasasivam and M. Uvais S. Sultanbawa
pg 612; DOI:
10.1039/P19750000612
PDF
Reactions of chlorotrifluoromethyldisulphane
Neil R. Zack and Jean'Ne M. Shreeve
pg 614; DOI:
10.1039/P19750000614
PDF

Issue 7


Contents pages

pg P015; DOI:
10.1039/P197500FP015
PDF
Structure of lithocarpic lactone, a new triterpenoid from two Lithocarpus species of Hong Kong
(Miss) Wai-Haan Hui Man Moon Li and (Miss) Yuk-Chun Lee
pg 617; DOI:
10.1039/P19750000617
PDF
Rapid intramolecular collapse of betaines derived from 5-phenyldibenzophospholes as compared with those derived from acyclic triarylphosphines; mechanism of the Wittig reaction in protic solvents
David W. Allen Barrie G. Hutley and Keith Polasik
pg 619; DOI:
10.1039/P19750000619
PDF
Azabenzocycloheptenones. Part XVIII. Amines and amino-ketones of the tetrahydro-3-benzazepin-1-one series
Mary Lennon Angus McLean George R. Proctor and Ian W. Sinclair
pg 622; DOI:
10.1039/P19750000622
PDF
Reaction of chlorosulphonyl isocyanate with ethyl 4,6-di-O-acetyl-2,3-dideoxy--D-erythro-hex-2-enopyranoside: a reinvestigation
Richard H. Hall Amor Jordaan and Olof G. de Villiers
pg 626; DOI:
10.1039/P19750000626
PDF
Synthesis and reactions of 12-aryl-1,2,3,4-tetrahydro-6H-indazolo-[2,1-a]benzotriazolium hydroxide inner salts and 8,9,10,11-tetrahydro-7,10,10-trimethyl-8-oxo-5H-indazolo[1,2-a]benzotriazolium hydroxide inner salt
Arthur J. Nunn and Frederick J. Rowell
pg 629; DOI:
10.1039/P19750000629
PDF
Heterocycles by cycloaddition. Part I. Cycloaddition–extrusion–ring expansion reactions of five-membered mesoionic compounds with diphenylcyclopropenone and related compounds: preparation of six-membered heterocycles
Hiroshi Matsukubo and Hiroshi Kato
pg 632; DOI:
10.1039/P19750000632
PDF
4-Phosphoranylidenebutenolide intermediates in the synthesis of 4-ylidenebutenolides and 4-ylidenetetronic acids. Synthesis of alkylidenephthalide constituents of celery odour and models for freelingyne
David W. Knight and Gerald Pattenden
pg 635; DOI:
10.1039/P19750000635
PDF
Synthesis of freelingyne, an acetylenic sesquiterpene from Eremophila freelingii
David W. Knight and Gerald Pattenden
pg 641; DOI:
10.1039/P19750000641
PDF
On the preparation of L-[2,3-3H2]phenylalanine and L-[2,3-3H2]tyrosine
Gordon W. Kirby Subramanian Narayanaswami and Poruri S. Rao
pg 645; DOI:
10.1039/P19750000645
PDF
An ESCA study of the fluoride-ion-induced trimerization product from pefluorocyclobutene
David T. Clark Richard D. Chambers and David B. Adams
pg 647; DOI:
10.1039/P19750000647
PDF
Synthesis of some acridines and 9-acridones for spectral studies
R. Morrin Acheson and Roger G. Bolton
pg 650; DOI:
10.1039/P19750000650
PDF
Reactions of perfluoroalkylcopper compounds. Part V. The preparation of some polyfluoroalkyl-substituted acids and alcohols
Paul L. Coe Nigel E. Milner and J. Anthony Smith
pg 654; DOI:
10.1039/P19750000654
PDF
Some base-catalysed ring expansion and ring expansion–ring contraction reactions of ethyl 4-chloromethyl-1,2,3,4-tetrahydro-6-methyl-2-oxopyrimidine-5-carboxylate
John Ashby and David Griffiths
pg 657; DOI:
10.1039/P19750000657
PDF
Studies in terpenoid biosynthesis. Part XIII. The biosynthetic relationship of the gibberellins in Gibberella fujikuroi
Roger Evans and James R. Hanson
pg 663; DOI:
10.1039/P19750000663
PDF
Isomerism in bicyclic diacetals. Part I. 1,3:2,4- and 1,4:2,3-Di-O-methylene-erythritol
Ian J. Burden and J. Fraser Stoddart
pg 666; DOI:
10.1039/P19750000666
PDF
Isomerism in bicyclic diacetals. Part II. Bicyclic methylene diacetals in the galacto, arabino, and ribo series
Ian J. Burden and J. Fraser Stoddart
pg 675; DOI:
10.1039/P19750000675
PDF
Branched-chain sugars. Part IV. Synthesis of derivatives of aldgarose, a component of aldgamycin E
John S. Brimacombe Jonathan Minshall and Clive W. Smith
pg 682; DOI:
10.1039/P19750000682
PDF
Natural acetylenes. Part XLVIII. Absolute configurations of a C7 diynol, a C9 diynetriol, and a C9 dihydroxy-diynone from fungal cultures
Malcolm R. Ord Christine M. Piggin and Viktor Thaller
pg 687; DOI:
10.1039/P19750000687
PDF
Biosynthesis of nepodin (2-acetyl-3-methylnaphthalene-1,8-diol) in Rumex alpinus L.
Hans-Joachim Bauch Rudi Paul Labadie and Eckhard Leistner
pg 689; DOI:
10.1039/P19750000689
PDF

Issue 8


Contents pages

pg P017; DOI:
10.1039/P197500FP017
PDF
Synthesis of isoxazolo[3,4-b]pyridin-3(1H)-one and isoxazolo[5,4-b]-pyridin-3(2H)-one
Mazhar Ali Khan and Fathi Kamel Rafla
pg 693; DOI:
10.1039/P19750000693
PDF
Oxymetallation. Part IX. Bromodemercuration of peroxymercurials derived from terminal, medial, and cyclic alkenes to give -bromoperoxides
A. J. Bloodworth and I. M. Griffin
pg 695; DOI:
10.1039/P19750000695
PDF
Free-radical reactions of halogenated bridged polycyclic compounds. Part XVII. Reaction of 5-alkyl-1,2,3,4,7,7-hexachloronorborna-2,5-dienes and 5-alkenyl-1,2,3,4,7,7-hexachloronorborn-2-enes with N-bromosuccinimide
David R. Adams and David I. Davies
pg 698; DOI:
10.1039/P19750000698
PDF
Organophosphorus chemistry. Part XVII. Reaction of hexafluoropropene and some fluorochloro-olefins with phosphines: competition between radical and ionic reactions
Peter Cooper Roy Fields and Robert N. Haszeldine
pg 702; DOI:
10.1039/P19750000702
PDF
Oxidation of aromatic substrates. Part II. The action of ruthenium tetraoxide on some derivatives of naphthalene and its monoazaanalogues
D. C. Ayres and A. M. M. Hossain
pg 707; DOI:
10.1039/P19750000707
PDF
Functionalization of methyl groups in isopimaran-8-ol, hopan-7-ol, and hopan-15-ol and derivatives
R. Edward Corbett and Alistair L. Wilkins
pg 710; DOI:
10.1039/P19750000710
PDF
Studies related to dihydro-1,4-thiazines. Part VII. Reaction of methyl (4S,6S)-5,5,9,9-tetramethyl-7-oxo-8-oxa-4-thia-1-azabicyclo-[4.3.0]non-2-ene-3-carboxylate 4-oxide with acetyl chloride
Richard J. Stoodley and Robert B. Wilkins
pg 716; DOI:
10.1039/P19750000716
PDF
Fungal products. Part XIV. Metabolic pathways from ent-kaurenoic acid to the fungal gibberellins in mutant B1-41a of Gibberella fujikuroi
John R. Bearder Jake MacMillan and Bernard O. Phinney
pg 721; DOI:
10.1039/P19750000721
PDF
The chemistry of santonene. Part X. Products of the action of phosphorus pentachloride on santonin
Andreas Fröhlich Kiyoyasu Ishikawa and T. Brian H. McMurry
pg 726; DOI:
10.1039/P19750000726
PDF
Photochemical transformations of the [4 + 2] dimeric adduct of 2-benzoylnorborna-2,5-diene and its derivatives
P. S. Venkataramani S. Chandrasekaran and S. Swaminathan
pg 730; DOI:
10.1039/P19750000730
PDF
Photo-substitution of 1,2,4,5-tetracyanobenzene by toluene
Akira Yoshino Kazuyuki Yamasaki Teijiro Yonezawa and Mamoru Ohashi
pg 735; DOI:
10.1039/P19750000735
PDF
Tetra- and hexa-dehydroyohimbane synthesis by an intermolecular cycloaddition of o-quinodimethane
Tetsuji Kametani Masahiro Kajiwara Tamiko Takahashi and Keiichiro Fukumoto
pg 737; DOI:
10.1039/P19750000737
PDF
Addition reactions of heterocyclic compounds. Part LX. Reactions of 2-substituted pyridines with acetylenic esters leading to quinolizines and pyrrolo[2,1,5-cd]indolizines
R. Morrin Acheson and John Woollard
pg 740; DOI:
10.1039/P19750000740
PDF
Addition reactions of heterocyclic compounds. Part LXI. Reactions of electrophilic acetylenes with conjugated cyclic enamines
R. Morrin Acheson and John Woollard
pg 744; DOI:
10.1039/P19750000744
PDF
Dithiols. Part XXVI. Conversion of aliphatic and alicyclic epoxides into trithiocarbonates
Md. Erfan Ali Nabil G. Kardouche and Leonard N. Owen
pg 748; DOI:
10.1039/P19750000748
PDF
Dithiols. Part XXVII. Conversion of aliphatic and alicyclic carbonates and thiocarbonates into trithiocarbonates
Nabil G. Kardouche and Leonard N. Owen
pg 754; DOI:
10.1039/P19750000754
PDF
Syntheses of dihydro-derivatives of the benzo[c]phenanthridine alkaloids avicine and nitidine by enamide photocyclisation
Ichiya Ninomiya Takeaki Naito Hisashi Ishii Toshiaki Ishida Miyoko Ueda and Kenichi Harada
pg 762; DOI:
10.1039/P19750000762
PDF
Electrocyclic reactions. Part VI. Thermal reactions of 1,5-diphenylpentadienide ion and the anions derived from cis- and trans-3,4-diphenylcyclopentene
Charles W. Shoppee and George N. Henderson
pg 765; DOI:
10.1039/P19750000765
PDF
Cyclic products from sulphonamides and formaldehyde
Orfeo O. Orazi and Renée A. Corral
pg 772; DOI:
10.1039/P19750000772
PDF
Studies of heterocyclic compounds. Part XVII. Synthesis of 1,6-Dioxa-6a-thia- and 1,6-dioxa-6a-selena-pentalenes
David H. Reid and Robert G. Webster
pg 775; DOI:
10.1039/P19750000775
PDF
Highly fluorinated heterocycles. Part XIII. Fluorination of 1-methylpyrrole and some reactions of derived compounds
Paul L. Coe Peter Smith J. Colin Tatlow and Michael Wyatt
pg 781; DOI:
10.1039/P19750000781
PDF

Issue 9


Contents pages

pg P019; DOI:
10.1039/P197500FP019
PDF
Synthesis of methyl gentosaminide, methyl 3-deoxy-3-methylaminoarabinopyranoside, and related amino-sugars
David J. Cooper D. Huw Davies Alan K. Mallams and Albert S. Yehaskel
pg 785; DOI:
10.1039/P19750000785
PDF
Synthesis and acid-catalysed rearrangement of (1R,2R,5S,6S)-Tricyclo[4.3.1.1]undecane
Naotake Takaishi Yoshiaki Inamoto and Koji Aigami
pg 789; DOI:
10.1039/P19750000789
PDF
Synthesis of 9,11-disubstituted 19-nor-steroids
Robert V. Coombs Judit Koletar Robert P. Danna and Henry Mah
pg 792; DOI:
10.1039/P19750000792
PDF
Reaction of dimethyl imidazole-4,5-dicarboxylate with styrene oxide
G. Cooper and W. J. Irwin
pg 798; DOI:
10.1039/P19750000798
PDF
A synthetic route to 3,7-disubstituted bicyclo[3.3.2]decanes
Rodney S. Henry W. Thomas Moodie William Parker and C. Ian F. Watt
pg 803; DOI:
10.1039/P19750000803
PDF
Bis(trimethylsilyloxy)alkenes from the modified acyloin reaction of Schrpler and Rhlmann; stereochemical considerations
Clive M. Cookson and Gordon H. Whitham
pg 806; DOI:
10.1039/P19750000806
PDF
Deoxygenation of some 3-oxo-steroids by chlorotrimethylsilane and zinc
Philip Hodge and Munir N. Khan
pg 809; DOI:
10.1039/P19750000809
PDF
Reactions of quinones with aromatic ethers. Part VI. Triphenylenols from mono- and di-chlorobenzoquinones and veratrole
Robert Buchan and Oliver C. Musgrave
pg 811; DOI:
10.1039/P19750000811
PDF
Structures of the aminoglycoside antibiotics 66–40B and 66–40D produced by Micromonospora inyoensis
D. Huw Davies Diane Greeves Alan K. Mallams James B. Morton and Richard W. Tkach
pg 814; DOI:
10.1039/P19750000814
PDF
Studies concerning the antibiotic actinonin. Part I. The constitution of actinonin. A natural hydroxamic acid with antibiotic activity
James J. Gordon John P. Devlin Anthony J. East W. David Ollis Ian O. Sutherland Derek E. Wright and Léon Ninet
pg 819; DOI:
10.1039/P19750000819
PDF
Studies concerning the antibiotic actinonin. Part II. Total synthesis of actinonin and some structural analogues by the isomaleimide method
Nicholas H. Anderson W. David Ollis John E. Thorpe and A. David Ward
pg 825; DOI:
10.1039/P19750000825
PDF
Studies concerning the antibiotic actinonin. Part III. Synthesis of structural analogues of actinonin by the anhydride–imide method
John P. Devlin W. David Ollis John E. Thorpe (the late) Ronald J. Wood Barbara J. Broughton Peter J. Warren Kenneth R. H. Wooldridge and Derek E. Wright
pg 830; DOI:
10.1039/P19750000830
PDF
Studies concerning the antibiotic actinonin. Part IV. Synthesis of structural analogues of actinonin by the mixed anhydride method
Barbara J. Broughton Peter J. Warren Kenneth R. H. Wooldridge Derek E. Wright W. David Ollis and (the late) Ronald J. Wood
pg 842; DOI:
10.1039/P19750000842
PDF
Studies concerning the antibiotic actinonin. Part V. Synthesis of structural analogues of actinonin by the anhydride–ester method
John P. Devlin W. David Ollis and John E. Thorpe
pg 846; DOI:
10.1039/P19750000846
PDF
Studies concerning the antibiotic actinonin. Part VI. Synthesis of structural analogues of actinonin by dicyclohexylcarbodi-imide coupling reactions
John P. Devlin W. David Ollis John E. Thorpe and Derek E. Wright
pg 848; DOI:
10.1039/P19750000848
PDF
Studies concerning the antibiotic actinonin. Part VII. Mass spectra of actinonin and related compounds
Nicholas H. Anderson John P. Devlin Stephen Jones W. David Ollis and John E. Thorpe
pg 852; DOI:
10.1039/P19750000852
PDF
Studies concerning the antibiotic actinonin. Part VIII. Structure–activity relationships in the actinonin series
Barbara J. Broughton Peter Chaplen Wilfred A. Freeman Peter J. Warren Kenneth R. H. Wooldridge and Derek E. Wright
pg 857; DOI:
10.1039/P19750000857
PDF
Ring c functionalised diterpenoids. Part V. Preparation and formolysis of (16S)-ent-12-p-tolylsulphonyloxykaurane and the (16S)-ent-13-p-tolylsulphonyloxyatisanes
Alan J. McAlees and Robert McCrindle
pg 861; DOI:
10.1039/P19750000861
PDF
Cope rearrangement of some germacrane-type furan sesquiterpenes. Part V. Preparation and thermal rearrangement of some cis,trans-germacranolides
Ken'ichi Takeda and Isao Horibe
pg 870; DOI:
10.1039/P19750000870
PDF

Issue 10


Contents pages

pg P021; DOI:
10.1039/P197500FP021
PDF
Fusicoccin. Part IV. The structure of fusicoccin J
Kevin D. Barrow Derek H. R. Barton (Sir) Ernst Chain Desire Bageenda-Kasujja and Graham Mellows
pg 877; DOI:
10.1039/P19750000877
PDF
Studies related to penicillins. Part XVI. Preparation of methyl 2-{(1S,5R)-3-benzyl-7-oxo-4-oxa-2,6-diazabicyclo[3.2.0]hept-2-en-6-yl}-3-methylbut-2-enoate
Richard J. Stoodley and Nigel S. Watson
pg 883; DOI:
10.1039/P19750000883
PDF
An approach to the synthesis of (3R)- and (3S)-2,3-epoxysqualene
Mohamed A. Abadallah and Jayant N. Shah
pg 888; DOI:
10.1039/P19750000888
PDF
Reaction of an asymmetric imidazolinium compound with nucleophiles
Isabel Perillo and Samuel Lamdan
pg 894; DOI:
10.1039/P19750000894
PDF
Synthesis of ()-presqualene alcohol, ()-prephytoene alcohol, and structurally related compounds
Rodwill V. M. Campbell Leslie Crombie David A. R. Findley Richard W. King Gerald Pattenden and Donald A. Whiting
pg 897; DOI:
10.1039/P19750000897
PDF
Carbon-13-magnetic resonance spectra. Synthetic presqualene esters, related cyclopropanes, and isoprenoids
Leslie Crombie Richard W. King and Donald A. Whiting
pg 913; DOI:
10.1039/P19750000913
PDF
D-Homo-steroids. Part IV. Acetolysis of D-homo-5-androstan-17a-yl tosylate: a novel rearrangement involving the steroid backbone
Ismail Khattak David N. Kirk Catherine M. Peach and Malcolm A. Wilson
pg 916; DOI:
10.1039/P19750000916
PDF
Reactions of heterocycles with thiophosgene. Part IV. ,4-Dichloro-2-isothiocyanatocinnamaldehyde, a product from 4,7-Dichloroquinoline
Roy Hull Mrs Patricia J. van den Broek and Michael L. Swain
pg 922; DOI:
10.1039/P19750000922
PDF
A new synthesis of 1,4-dihydropyridines
Tomy Chennat and Ulli Eisner
pg 926; DOI:
10.1039/P19750000926
PDF
Reduction of 3,5-disubstituted pyridines to dihydropyridines
Evans Booker and Ulli Eisner
pg 929; DOI:
10.1039/P19750000929
PDF
Methyl transfer: the mass spectra of reserpine derivatives
Tetsuji Kametani Yasuo Fujimoto Yoshio Suzuki Yoshiro Tanaka Kiyosato Nyu Tohru Yamanaka and Shigeo Ikeda
pg 932; DOI:
10.1039/P19750000932
PDF
The synthesis of oligoribonucleotides. Part XI. Preparation of ribonucleoside 2-acetal 3-esters by selective deacylation
Colin B. Reese J. Charles M. Stewart Jacques H. van Boom Harry P. M. de Leeuw Joek Nagel and Jan F. M. de Rooy
pg 934; DOI:
10.1039/P19750000934
PDF
Demethoxyviridin and demethoxyviridiol: new fungal metabolites
David C. Aldridge W. Brian Turner Alexander J. Geddes and Bernard Sheldrick
pg 943; DOI:
10.1039/P19750000943
PDF
Identification of three new pterocarpans (6a,11a-dihydro-6H-benzofuro[3,2-c][1]benzopyrans) from Pisum sativum infected with Fusarium solani f. sp. pisi
Steven G. Pueppke and Hans D. VanEtten
pg 946; DOI:
10.1039/P19750000946
PDF
Remote anodic oxidation of carboxylic acids in fluorosulphuric acid: a synthesis of lactones and unsaturated cyclic ketones
Derek Pletcher and Carmen Z. Smith
pg 948; DOI:
10.1039/P19750000948
PDF
Electrochemical preparation of bismethylsulphonyl peroxide and its reactions with aromatic hydrocarbons
Christopher J. Myall and Derek Pletcher
pg 953; DOI:
10.1039/P19750000953
PDF
Medicinal nitro-compounds. Part II. Search for ortho-interactions in tumour-inhibitory 2,4-dinitrophenylaziridines
Graham A. M. Butchart Malcolm F. G. Stevens and Brian C. Gunn
pg 956; DOI:
10.1039/P19750000956
PDF
Reaction of trifluoroacetic acid with chlorodiphenylphosphine
David J. H. Smith and Stuert Trippett
pg 963; DOI:
10.1039/P19750000963
PDF
A simple synthesis of anthracenes
Ian Fleming and Talat Mah
pg 964; DOI:
10.1039/P19750000964
PDF
Organosilicon chemistry. Part XIV. Insertion of 1,2,2-trifluoroethylidene into C–H bonds of tetra-alkylsilanes: a novel alkyl group rearrangement
Robert N. Haszeldine Anthony E. Tipping and Richard O' B. Watts
pg 966; DOI:
10.1039/P19750000966
PDF
Electro-organic reactions. Part IV. Preparative aspects of the cathodic hydrogenation of activated carbon–carbon double bonds
L. Alberto Avaca and James H. P. Utley
pg 971; DOI:
10.1039/P19750000971
PDF
6-Substituted s-triazolo[4,3-b]-s-tetrazine-3-thiols: a sensitive and specific test for aldehydes
Ronald G. Dickinson and Noel W. Jacobsen
pg 975; DOI:
10.1039/P19750000975
PDF
Syntheses of derivatives of 2,6-diamino-2,3,4,6-tetradeoxy-D-erythro-hexose (purpurosamine C), a component of gentamycin C1a
John S. Brimacombe Ibrahim Da'aboul and Leslie C. N. Tucker
pg 979; DOI:
10.1039/P19750000979
PDF

Issue 11


Contents pages

pg P023; DOI:
10.1039/P197500FP023
PDF
Some structural features of Pneumococcus Type XXII capsular polysaccharide
Bishnu P. Chatterjee and Chintalacharuvu V. N. Rao
pg 985; DOI:
10.1039/P19750000985
PDF
Novel synthesis of -substituted -diphenylmethylstyrenes from -substituted -methylstyrenes in the presence of palladium(II) acetate
Kimiaki Yamamura
pg 988; DOI:
10.1039/P19750000988
PDF
Application of 13C nuclear magnetic resonance to the study of gibberellins
Isomaro Yamaguchi Nobutaka Takahashi and Kenichi Fujita
pg 992; DOI:
10.1039/P19750000992
PDF
Elucidation of the structure of gibberellin A40 from Gibberella fujikuroi
Isomaro Yamaguchi Masaharu Miyamoto Hisakazu Yamane Noboru Murofushi Nobutaka Takahashi and Kenichi Fujita
pg 996; DOI:
10.1039/P19750000996
PDF
8-Ethylidene-7,8-dihydro-4-methoxypyrano[4,3-b]pyran-2,5-dione (coarctatin), a metabolite of Chaetomium coarctatum
Brian F. Burrows W. Brian Turner and Edward R. H. Walker
pg 999; DOI:
10.1039/P19750000999
PDF
Keten. Part XIV. Adducts of diphenylketen with aza-arenes
Giles A. Taylor
pg 1001; DOI:
10.1039/P19750001001
PDF
Elaboration of sclareol by Claisen rearrangement
John M. Mellor and Julio A. M. da Cunha Pinto
pg 1009; DOI:
10.1039/P19750001009
PDF
Studies on the syntheses of heterocyclic compounds. Part DXCVII. Novel formation of benzo[5,6]cyclohept[1,2,3-ij]isoquinolines from berbinium salts
Tetsuji Kametani Makoto Takemura Keiichi Takahashi Mitsuhiro Takeshita Masataka Ihara and Keiichiro Fukumoto
pg 1012; DOI:
10.1039/P19750001012
PDF
Correlation of circular dichroism and conformation in - and ?-unsaturated ketones
Graham P. Powell Richard N. Totty and John Hudec
pg 1015; DOI:
10.1039/P19750001015
PDF
Spectroscopic properties of axially and equatorially substituted -trimethylstannyl ketones and compounds with related chromophores
John Hudec
pg 1020; DOI:
10.1039/P19750001020
PDF
Triazines and related products. Part XV. 2,4-Diaminopyrimidines and 2-aminopyrimidin-4(3H)-ones bearing 1,2,3-benzotriazinyl groups as potential dihydrofolic reductase inhibitors
Thomas B. Brown and Malcolm F. G. Stevens
pg 1023; DOI:
10.1039/P19750001023
PDF
Polyfluorocarbanion chemistry. Part II. Fluoride-initiated reactions of hexafluoropropene with pentafluoropyridine and tetrafluoropyridine-4-carbonitrile
Colin J. Drayton William T. Flowers and Robert N. Haszeldine
pg 1029; DOI:
10.1039/P19750001029
PDF
Polyfluorocarbanion chemistry. Part III. Reaction of hexafluoropropene with pentafluorobenzonitrile
Colin J. Drayton William T. Flowers Robert N. Haszeldine and William D. Morton
pg 1035; DOI:
10.1039/P19750001035
PDF
Rearrangements in a series of thiazol-2-ylsemicarbazides
Sidney S. Berg Barry J. Peart and Malcolm P. Toft
pg 1040; DOI:
10.1039/P19750001040
PDF
4,8,8-Tribromobicyclo[5.1.0]oct-4-en-3-ones from dibromocarbene adducts of cyclohexa-1,4-dienols
A. K. Yagoub and George M. Iskander
pg 1043; DOI:
10.1039/P19750001043
PDF
Decomposition and cycloaddition reactions of some bis(azodicarbonyl) compounds
William G. Barrett and Donald Mackay
pg 1046; DOI:
10.1039/P19750001046
PDF
Carbonyl and thiocarbonyl compounds. Part XIV. Reactions of tetrachloro-o-benzoquinone with 3-(2-furyl)- and 3-(2-thienyl)-acrylophenones
Nazih Latif Nawal Mishriky and Nabih S. Girgis
pg 1052; DOI:
10.1039/P19750001052
PDF
Anodic oxidation. Part XIII. Products from bicyclo[2.2.1]hept-2-ene, bicyclo[2.2.1]hepta-2,5-diene, and tetracyclo[3.2.0.02,7.04,6]heptane
Alan J. Baggaley Roger Brettle and John R. Sutton
pg 1055; DOI:
10.1039/P19750001055
PDF
Aromatic annelation by reaction of aryl radicals with dimethyl acetylenedicarboxylate and related compounds
Brian D. Baigrie John Brennan J. I. G. Cadogan John Cook and John T. Sharp
pg 1060; DOI:
10.1039/P19750001060
PDF
Reaction of phenyl radicals with dialkyl azodiformates: formation of, and nuclear magnetic resonance studies of conformational restrictions in, tetra-alkyl 1,4-diphenyltetra-azane-1,2,3,4-tetracarboxylates
Brian D. Baigrie J. I. G. Cadogan and John T. Sharp
pg 1065; DOI:
10.1039/P19750001065
PDF
Radical phthalimidation of aromatic compounds by photolysis of N-tosyloxyphthalimide: a route to primary aromatic amines
J. I. G. Cadogan and Alan G. Rowley
pg 1069; DOI:
10.1039/P19750001069
PDF
A note on three routes to benzyne: decomposition of diphenyliodonium acetate, nitrosation of N-phenylphosphylamidates, and deoxygenation of benzenediazotoluene-p-sulphonate N-oxide (cupferron tosylate) by phosphorus trichloride
J. I. G. Cadogan Alan G. Rowley John T. Sharp Bohdan Sledzinski and Norman H. Wilson
pg 1072; DOI:
10.1039/P19750001072
PDF
Fluorinated acetylenes. Part VI. Some thermal and photochemical reactions of NN-bistrifluoromethylamino-substituted acetylenes
John Freear and Anthony E. Tipping
pg 1074; DOI:
10.1039/P19750001074
PDF

Issue 12


Contents pages

pg P027; DOI:
10.1039/P197500FP027
PDF
Conversion of secopenicillanic acid derivatives into -lactam sulphimides and oxazolines
Malcolm M. Campbell and Graham Johnson
pg 1077; DOI:
10.1039/P19750001077
PDF
Heterogeneous catalytic hydrogenation of allenes over supported palladium: selectivity, stereoselectivity, and regioselectivity
Leslie Crombie Peter A. Jenkins and David A. Mitchard
pg 1081; DOI:
10.1039/P19750001081
PDF
Absolute configuration of allenes, conversion of molecular dissymmetry into centrodissymmetry by heterogeneous catalytic hydrogenation
Leslie Crombie Peter A. Jenkins and John Roblin
pg 1090; DOI:
10.1039/P19750001090
PDF
Reduction of allenes and acetylenes by catalytic and chemical methods: molecular queueing effects in competitive hydrogenation
Leslie Crombie Peter A. Jenkins and John Roblin
pg 1099; DOI:
10.1039/P19750001099
PDF
Synthesis and biological activity of 2-hydroxyvitamin D3
Chikara Kaneko Sachiko Yamada Akiko Sugimoto Masayuki Ishikawa Tatsuo Suda Michiko Suzuki and Satoshi Sasaki
pg 1104; DOI:
10.1039/P19750001104
PDF
A rearrangement of 4,5-epoxy-6-hydroxyandrostan-17-yl acetate
Derek Baldwin and James R. Hanson
pg 1107; DOI:
10.1039/P19750001107
PDF
The 13C nuclear magnetic resonance spectra of some methyloestratrienes; application to the mechanism of their formation
James R. Hanson and Michael Siverns
pg 1110; DOI:
10.1039/P19750001110
PDF
Naturally occurring quinones. Part XXV. Pterocarpenequinones (6H-benzofuro[3,2-c][1]benzopyranquinones) from Brya ebenus
Margarida A. Ferreira Michael Moir and Ronald H. Thomson
pg 1113; DOI:
10.1039/P19750001113
PDF
Persulphate oxidations. Part XI. Oxidative dimerisation of aminonaphthoquinones
Alexander R. Forrester Alexander S. Ingram I. Lennox John and Ronald H. Thomson
pg 1115; DOI:
10.1039/P19750001115
PDF
A procedure for rapid recognition of the rings of a molecule
Ashmeed Esack
pg 1120; DOI:
10.1039/P19750001120
PDF
Computer manipulation of central chirality
Ashmeed Esack and Malcolm Bersohn
pg 1124; DOI:
10.1039/P19750001124
PDF
Photochemistry of halogenocarbon compounds. Part II. Valence isomers from fluorinated pyridazines
Richard D. Chambers Jerzy R. Maslakiewicz and Krishna C. Srivastava
pg 1130; DOI:
10.1039/P19750001130
PDF
Investigations on the biosynthesis of steroids and terpenoids. Part XII. Biosynthesis of 3-hydroxy-triterpenoids and -steroids from (3S)-2,3-epoxy-2,3-dihydrosqualene
Derek H. R. Barton Trevor R. Jarman Keith C. Watson David A. Widdowson Robin B. Boar and Kathleen Damps
pg 1134; DOI:
10.1039/P19750001134
PDF
Synthesis of 10-benzoyl-9-acridone and 9-acridone from 2,2- and 2,3-disubstituted benzophenones
Guo-Shyoung J. Chen and Martin S. Gibson
pg 1138; DOI:
10.1039/P19750001138
PDF
Biosynthesis. Part XXI. Investigations on the biosynthesis of stylopine in Chelidonium majus
Alan R. Battersby R. John Francis Maurice Hirst Edmundo A. Ruveda and James Staunton
pg 1140; DOI:
10.1039/P19750001140
PDF
Biosynthesis. Part XXII. The origin of chelidonine and of other alkaloids derived from the tetrahydroprotoberberine skeleton
Alan R. Battersby James Staunton Hugh R. Wiltshire R. John Francis and Robert Southgate
pg 1147; DOI:
10.1039/P19750001147
PDF
Studies of enzyme-mediated reactions. Part IV. Complementary syntheses of stereospecifically labelled (R)- and (S)-[-3H1]benzyl alcohol derivatives by use of liver alcohol dehydrogenase
Alan R. Battersby James Staunton and Hugh R. Wiltshire
pg 1156; DOI:
10.1039/P19750001156
PDF
Studies of enzyme-mediated reactions. Part V. Synthesis of (13S)- and (13R)-[13-3H1]scoulerine from stereospecifically labelled (R)- and (S)-[3H1]benzyl alcohols; stereochemistry of enzymic reactions at saturated benzylic carbon
Alan R. Battersby James Staunton Hugh R. Wiltshire Brian J. Bircher and Claudio Fuganti
pg 1162; DOI:
10.1039/P19750001162
PDF
Bicyclic analogues of exaltone (cyclopentadecanone) and muscone (3-methylcyclopentadecanone)
Bruce A. McAndrew and Stephen W. Russell
pg 1172; DOI:
10.1039/P19750001172
PDF
Isomerism of 1- and 2-(NN-disubstituted aminomethyl)benzotriazoles; an investigation by nuclear magnetic resonance spectroscopy
John R. Lindsay Smith and John S. Sadd
pg 1181; DOI:
10.1039/P19750001181
PDF

Issue 13


Contents pages

pg P029; DOI:
10.1039/P197500FP029
PDF
Amino-acids and peptides. Part XXXVIII. Use of 4-picolyloxycarbonylhydrazides as handles to facilitate peptide synthesis. Synthesis of fragments related to porcine gastric inhibitory polypeptide
Robert Macrae and Geoffrey T. Young
pg 1185; DOI:
10.1039/P19750001185
PDF
C-nucleoside studies. Part II. Pentofuranosylethynes from 2,3-O-isopropylidene-D-ribose
J. Grant Buchanan Allan D. Dunn and Alan R. Edgar
pg 1191; DOI:
10.1039/P19750001191
PDF
Synthesis of oxazolines from epoxides
John R. Lindsay Smith Richard O. C. Norman and Michael R. Stillings
pg 1200; DOI:
10.1039/P19750001200
PDF
Microbiological hydroxylation of 17-norkauran-16-one and ent-17-norkauran-16-one with the fungus Rhizopus nigricans
Robert McCrindle James K. Turnbull and Allan B. Anderson
pg 1202; DOI:
10.1039/P19750001202
PDF
Transformations of penicillins: reactions with chloramine T
Malcolm M. Campbell Graham Johnson A. F. Cameron and I. R. Cameron
pg 1208; DOI:
10.1039/P19750001208
PDF
Transformations of penicillins: novel ring-opening reactions of a penicillin-derived sulphimide
Malcolm M. Campbell and Graham Johnson
pg 1212; DOI:
10.1039/P19750001212
PDF
Stereospecific conversion of epoxides into olefins
John M. Behan Robert A. W. Johnstone and Malcolm J. Wright
pg 1216; DOI:
10.1039/P19750001216
PDF
The chemistry of terpenes. Part XIX. Reaction of (+)-3,4-epoxycarane with halogen acids and acetic acid
Wesley Cocker and David H. Grayson
pg 1217; DOI:
10.1039/P19750001217
PDF
Apicophilicity of the benzoyl group in five-co-ordinate phosphoranes
Stuart Trippett and Peter J. Whittle
pg 1220; DOI:
10.1039/P19750001220
PDF
Reactions of tellurium(IV) halides with anthracene and other organic compounds
Michael Albeck and Sason Shaik
pg 1223; DOI:
10.1039/P19750001223
PDF
Synthesis of di- and tetra-substituted 1,4,5,8-tetra-azaphenanthrenes (pyrazino[2,3-f]quinoxalines)
R. Nasielski-Hinkens and M. Benedek-Vamos
pg 1229; DOI:
10.1039/P19750001229
PDF
Reactions of palladium(II) with organic compounds. Part IV. Oxidation of some substituted stilbenes
Ferrers R. S. Clark Richard O. C. Norman and C. Barry Thomas
pg 1230; DOI:
10.1039/P19750001230
PDF
Action of acids and alkylating agents on 1,4-di-(2-pyridyl)tetraz-2-enes
Stephen Anderson Edward E. Glover and Kenneth D. Vaughan
pg 1232; DOI:
10.1039/P19750001232
PDF
Synthesis of a dithieno[2,3-b:3,2-e][1,4]thiazine and of di-3-thienylamine
Cor J. Grol
pg 1234; DOI:
10.1039/P19750001234
PDF
Carboxymethylation of p,-tetramethylstyrene by manganese(III) acetate. Reductive cyclization during treatment of the derived -aryl--lactone with polyphosphoric acid to give 4-isopropyl-7-methyl-1-tetralone
Ramachandra B. Mane and G. S. Krishna Rao
pg 1235; DOI:
10.1039/P19750001235
PDF
A simple synthesis of enamides from ketoximes
Robin B. Boar James F. McGhie Mick Robinson Derek H. R. Barton David C. Horwell and Robert V. Stick
pg 1237; DOI:
10.1039/P19750001237
PDF
A new and convenient synthesis of the 17,21-diacetoxy-20-oxopregnane side-chain
Robin B. Boar James F. McGhie Mick Robinson and Derek H. R. Barton
pg 1242; DOI:
10.1039/P19750001242
PDF
Alangiside, the monoterpenoid alkaloidal glycoside from Alangium lamarckii Thw.
Aboo Shoeb Kanwal Raj Randhir S. Kapil and Satya P. Popli
pg 1245; DOI:
10.1039/P19750001245
PDF
Pyrrolopyrimidine nucleosides. Part X. Synthesis of certain 4,5-disubstituted 7-(-D-ribofuranosyl)pyrrolo[2,3-d]pyrimidines related to toyocamycin and sangivamycin
Barbara C. Hinshaw Olga Leonoudakis Karl H. Schram and Leroy B. Townsend
pg 1248; DOI:
10.1039/P19750001248
PDF
Pyrrolopyrimidine nucleosides. Part XI. Influence of amino-groups at C-4 and C-6 or an amino-group at C-6 on the reactivity of a 5-cyano-group in pyrrolo[2,3-d]pyrimidine nucleosides
Karl H. Schram and Leroy B. Townsend
pg 1253; DOI:
10.1039/P19750001253
PDF
Bicyclic nucleosides related to pyrimidine nucleosides. Part III. 3-(-D-ribofuranosyl)isoguanine
Charles L. Schmidt and Leroy B. Townsend
pg 1257; DOI:
10.1039/P19750001257
PDF
Diazepines. Part XX. The properties of 2,3-dihydro-1,4-diazepinium perchlorate
Douglas Lloyd Hamish McNab and Donald R. Marshall
pg 1260; DOI:
10.1039/P19750001260
PDF
Electrochemical fluorination. Part I. Electrochemical fluorination of alkyl-substituted pyridines
Victor J. Davis Robert N. Haszeldine and Anthony E. Tipping
pg 1263; DOI:
10.1039/P19750001263
PDF
Metal ions and complexes in organic reactions. Part XX. Copper-catalysed reactions of aromatic bromo-carboxylates with carbanions, giving oxo-acids, isocoumarins, and related products
Reginald G. R. Bacon and John C. F. Murray
pg 1267; DOI:
10.1039/P19750001267
PDF
Chemistry of alkali metal tetracarbonylferrates. A simple method for alkylating and arylating carbonyl compounds and active methylene compounds
Gian Franco Cainelli Mauro Panunzio and Achille Umani-Ronchi
pg 1273; DOI:
10.1039/P19750001273
PDF
On the relationship between intramolecular hydrogen abstraction by alkoxyl radicals and deshielding by the corresponding hydroxy-groups as indicated by nuclear magnetic resonance
Robin B. Boar
pg 1275; DOI:
10.1039/P19750001275
PDF
Some reactions of 2-oxocyclopentanedithiocarboxylic acid and 3-methyl-5-oxo-1-phenyl-2-pyrazoline-4-dithiocarboxylic acid
Tatsuo Takeshima Naoaki Fukada Eiichi Okabe Fukashi Mineshima and Motomu Muraoka
pg 1277; DOI:
10.1039/P19750001277
PDF
Some benzazocinecarboxylic acids as potential anti-inflammatory agents
Geraint Jones and Gwenda T. Tringham
pg 1280; DOI:
10.1039/P19750001280
PDF
Reaction of diazomethane with quaternary nitrogen compounds to form betaines
Siegfried E. Drewes Herbert E. M. Magojo and Donald A. Sutton
pg 1283; DOI:
10.1039/P19750001283
PDF
Iodination of dibenzoylmethanes with iodine–peracetic acid
Iwao Urasaki and Yoshiro Ogata
pg 1285; DOI:
10.1039/P19750001285
PDF
18-Norpregna-8,11,13-trienes: reaction of 16,17-epoxypregn-8-en-11-ones with Lewis acids
Colin L. Hewett James Redpath and David S. Savage
pg 1288; DOI:
10.1039/P19750001288
PDF
Branched-chain sugars. Part V. Identification and synthesis of vinelose
John S. Brimacombe Safia Mahmood and Anthony J. Rollins
pg 1292; DOI:
10.1039/P19750001292
PDF
Methods of peptide sequencing. Part I. Conversion of oligopeptides into cyclic dipeptides: a gas chromatographic–mass spectrometric study
Robert A. W. Johnstone and T. Jeffery Povall
pg 1297; DOI:
10.1039/P19750001297
PDF
Selective rapid transfer-hydrogenation of aromatic nitro-compounds
Ian D. Entwistle Robert A. W. Johnstone and T. Jeffery Povall
pg 1300; DOI:
10.1039/P19750001300
PDF
Adducts from acyl chlorides and 2-unsubstituted oxazolines: formation and reactions
Bernard T. Golding and David R. Hall
pg 1302; DOI:
10.1039/P19750001302
PDF

Issue 14


Contents pages

pg P031; DOI:
10.1039/P197500FP031
PDF
Reactions of 154,2,4-triazoline-3,5-dione decomposition products with organophosphorus nucleophiles
Walter Lwowski and Brian J. Walker
pg 1309; DOI:
10.1039/P19750001309
PDF
Base-catalysed intramolecular cycloadditions of allyl 3-phenylprop-2-ynyl ethers and 4-methylpent-4-en-2-ynyl prop-2-ynyl ethers
A. Josephine Bartlett Trevor Laird and W. David Ollis
pg 1315; DOI:
10.1039/P19750001315
PDF
Thermal degradation of actinomycins to dioxopiperazines
Anthony B. Mauger
pg 1320; DOI:
10.1039/P19750001320
PDF
Monobutylidene acetals of 1-deoxy-D-galactitol
Trevor G. Bonner Edward J. Bourne David Lewis and Levant Yüceer
pg 1323; DOI:
10.1039/P19750001323
PDF
Application of functionalised 1,3-dipoles to the synthesis of fused heterocycles
B. Erik Landberg and J. William Lown
pg 1326; DOI:
10.1039/P19750001326
PDF
5,8-Dihydroxy-2-(4-methylpent-3-enyl)-1,4-naphthoquinone and its 2-[4-methyl-1-(2-methylcrotonoyloxy)pent-3-enyl] analogue (shikonin angelate) from Alkanna hirsutissima
Mohammad Afzal and Mikdad Tofeeq
pg 1334; DOI:
10.1039/P19750001334
PDF
Synthesis of pyrano[3,2-c]pyranthiones; characteristic shifts in the 1H nuclear magnetic resonance spectra of thiones
Francis M. Dean John Goodchild Andrew W. Hill Stephen Murray and Asif Zahman
pg 1335; DOI:
10.1039/P19750001335
PDF
Syntheses of isobenzofuran-4,7-quinone and isoindole-4,7-quinone
Gordon M. L. Cragg Robin G. F. Giles and Gregory H. P. Roos
pg 1339; DOI:
10.1039/P19750001339
PDF
Synthesis of pyridine oxides and isoxazolines from 4-(2-oxoalkylidene)-pyrans
Pierre Crabbé Jorge Haro Carlos Rius and Elvira Santos
pg 1342; DOI:
10.1039/P19750001342
PDF
Reactions of some dicarbonyl compounds. Part III. Oxidation of some -diketones with alkaline hydrogen peroxide
Wesley Cocker and David H. Grayson
pg 1347; DOI:
10.1039/P19750001347
PDF
Chemistry of the meliacins (limonoids). The structure of melianin A, a new protomeliacin from Melia azedarach
Joseph I. Okogun Christopher O. Fakunle Donald E. U. Ekong and Joseph D. Connolly
pg 1352; DOI:
10.1039/P19750001352
PDF
Microbiological hydroxylation. Part XVI. Incubation of derivatives (mainly acetals) of 5-androstane ketones with the fungi Calonectria decora, Aspergillus ochraceus, and Rhizopus nigricans
John M. Evans Sir Ewart R. H. Jones G. Denis Meakins John O. Miners Anthony Pendlebury and Alistair L. Wilkins
pg 1356; DOI:
10.1039/P19750001356
PDF
Microbiological hydroxylation. Part XVII. C-19 hydroxylation of 17-oxo-5-androstanes and 17-oxo-3,5-cyclo-5-androstanes by the fungus Calonectria decora
(Mrs.) Virginia E. M. Chambers William A. Denny Sir Ewart R. H. Jones G. Denis Meakins John O. Miners John T. Pinhey and Alistair L. Wilkins
pg 1359; DOI:
10.1039/P19750001359
PDF
Microbiological hydroxylation. Part XVIII. Introduction of 16-, 9-, and 3-hydroxy-groups into dioxygenated 5-androstanes by the fungus Diaporthe celastrina
Alan M. Bell A. David Boul Sir Ewart R. H. Jones G. Denis Meakins John O. Miners and Alistair L. Wilkins
pg 1364; DOI:
10.1039/P19750001364
PDF
Pyrylium salts. Part V. 5,6,12,13-Tetrahydro-5,13 : 6,12-bisepithiodibenzo[a,f]cyclodecene-7,14-diones by dimerisation of 2-benzothiopyrylium-4-olate
Kjell Undheim and Sigurd Baklien
pg 1366; DOI:
10.1039/P19750001366
PDF
Steroidal constituents of Physalis minima(Solanaceae)
Erwin Glotter Isaac Kirson Arieh Abraham Prabh D. Sethi and S. Sankara Subramanian
pg 1370; DOI:
10.1039/P19750001370
PDF
Photohydroxylation of anthraquinone in concentrated sulphuric acid
Gheorghe G. Mihai Peter G. Tarassoff and Nicolae Filipescu
pg 1374; DOI:
10.1039/P19750001374
PDF
Substituted naphthalenes and naphthols from benzynes and dienolate anions
Peter G. Sammes and Timothy W. Wallace
pg 1377; DOI:
10.1039/P19750001377
PDF
Reactions of octafluoroacridone and related compounds
David M. Owen Alan E. Pedler and J. Colin Tatlow
pg 1380; DOI:
10.1039/P19750001380
PDF
Synthesis of 1H-4,1,2-benzothiadiazines from substituted N-acetyl-N-aryl-N-thioaroylhydrazines
Patrick D. Callaghan Martin S. Gibson and Arthur J. Elliott
pg 1386; DOI:
10.1039/P19750001386
PDF
Heterocyclic syntheses from o-halogeno-acids. Part II. Thienopyridinones and thienopyranones from 3-bromothiophen-2- and 4-bromothiophen-3-carboxylic acids
Donald E. Ames and Odartey Ribeiro
pg 1390; DOI:
10.1039/P19750001390
PDF
1-S-(or Se)-dimethylstibino-derivatives of 1-thio- and 1-seleno--D-glucopyranose
Charles L. Baimbridge Charles D. Mickey and Ralph A. Zingaro
pg 1395; DOI:
10.1039/P19750001395
PDF
Oxidation of some trinuclear aromatic compounds with cerium(IV) ammonium nitrate
Bruno Rindone and Carlo Scolastico
pg 1398; DOI:
10.1039/P19750001398
PDF
Syntheses of gallic acid and pyrogallol
Mohammed T. Shipchandler C. Allan Peters and Charles D. Hurd
pg 1400; DOI:
10.1039/P19750001400
PDF
Concerning meso-tetraphenylporphyrin purification
Graham H. Barnett Mervyn F. Hudson and Kevin M. Smith
pg 1401; DOI:
10.1039/P19750001401
PDF
Steroids and related studies. Part XXXIII. Some steroidal tetrazoles
Harkishan Singh and Ravinder K. Malhotra
pg 1404; DOI:
10.1039/P19750001404
PDF
Fusicoccin. Part V. The biosynthesis of fusicoccin from [1-13C]- and [2-13C]-acetate
Kevin D. Barrow Robert B. Jones Phillip W. Pemberton and Lawrence Phillips
pg 1405; DOI:
10.1039/P19750001405
PDF
Unsaturated nitrogen compounds containing fluorine. Part V. Reactions of hexafluoroacetone azine with open-chain and cyclic hydrocarbon dienes
Stuart E. Armstrong and Anthony E. Tipping
pg 1411; DOI:
10.1039/P19750001411
PDF
-Dicyano-(1,3-dithiacyclobutane-2,4-diylidene)diacetamides (desaurins) from thiazine derivatives
Masataka Yokoyama
pg 1417; DOI:
10.1039/P19750001417
PDF
Heterocyclic polyfluoro-compounds. Part XXII. Synthesis of octafluoro-4,4-azopyridine and tetrafluoro-4-(pentafluorophenylazo)pyridine
Ronald E. Banks and Timothy J. Noakes
pg 1419; DOI:
10.1039/P19750001419
PDF
Synthesis of active forms of vitamin D. Part IX. Synthesis of 1,24-dihydroxycholecalciferol
Masuo Morisaki Naoyuki Koizumi Nobuo Ikekawa Toru Takeshita and Sachio Ishimoto
pg 1421; DOI:
10.1039/P19750001421
PDF
Methods of peptide sequencing. Part II. Cyclisation of N-2-amino-6-ntirophenyl and N-3-amino-2-pyridyl derivatives of amino-acids and peptides
Robert A. W. Johnstone T. Jeffrey Povall and Ian D. Entwistle
pg 1424; DOI:
10.1039/P19750001424
PDF
Nitrosoamide decomposition. A new method for selective degradation of amino-sugar-containing compounds
Jeffrey W. Llewellyn and J. Michael Williams
pg 1428; DOI:
10.1039/P19750001428
PDF

Issue 15


Contents pages

pg P033; DOI:
10.1039/P197500FP033
PDF
Synthesis of some 1,2,4-triazoles and 1,2,4-triazolines by reaction of oxamidrazone condensation products with acetic anhydride
Michael John Cooper Roy Hull and Michael Wardleworth
pg 1433; DOI:
10.1039/P19750001433
PDF
Parameters regulating the - and -cyclization of chalcones
Daneel Ferreira Edward V. Brandt Francois du R. Volsteedt and David G. Roux
pg 1437; DOI:
10.1039/P19750001437
PDF
Conversion of 2-chloroallylamines into heterocyclic compounds. Part I. 2-Methylindoles,1,5,6,7-tetrahdyro-3-methylindol-4-ones, and related heterocycles
Brian G. McDonald and George R. Proctor
pg 1446; DOI:
10.1039/P19750001446
PDF
D-Homo-steroids. Part V. A study of the mechanism of D-homoannulation of 17-hydroxypregnan-20-ones with boron trifluoride
David N. Kirk and Alan Mudd
pg 1450; DOI:
10.1039/P19750001450
PDF
X-Ray analysis of (Z)-2-p-methoxyphenylmethylenebenzofuran-3(2H)-one
Trevor J. King John S. Hastings and Harry G. Heller
pg 1455; DOI:
10.1039/P19750001455
PDF
Carotenoids and related compounds. Part XXX. Stereochemistry and synthesis of phytoene
Naeema Khan (née Khatoon) David E. Loeber Trevor P. Toube and Basil C. L. Weedon
pg 1457; DOI:
10.1039/P19750001457
PDF
Synthesis of hexahydroisoquinolines
T. A. Crabb and J. R. Wilkinson
pg 1465; DOI:
10.1039/P19750001465
PDF
Quinazolines. Part XXI. Synthesis of cis-2-amino-8a-carboxymethyl-3,4,4a,5,6,7,8,8a-octahydroquinazoline and related compounds. Conversion of perhydroquinazolin-2-ones into 2-amino-3,4,4a,5,6,7,8,8a-octahydroquinazolines
Wilfred L. F. Armarego and Phillip A. Reece
pg 1470; DOI:
10.1039/P19750001470
PDF
Chemical transformation of the dimeric dianion of 1,1-diphenylethylene
James G. Smith J. Richard Talvitie and Allan R. E. Eix
pg 1474; DOI:
10.1039/P19750001474
PDF
The stereochemistry of 2,4- and 2,3-disubstituted--butyrolactones
S. A. M. Tayyeb Hussain W. David Ollis Christopher Smith and J. Fraser Stoddart
pg 1480; DOI:
10.1039/P19750001480
PDF
Adduct formation between pyridine-2-thiones and acetylenic carbonyl derivatives
Kjell Undheim and Leif A. Riege
pg 1493; DOI:
10.1039/P19750001493
PDF
Carbon-13 magnetic resonance spectra of natural rotenoids and their relatives
Leslie Crombie Geoffrey W. Kilbee and Donald A. Whiting
pg 1497; DOI:
10.1039/P19750001497
PDF
Carbon-13 nuclear magnetic resonance spectra of the natural pyrethrins and related compounds
Leslie Crombie Gerald Pattenden and Derek J. Simmonds
pg 1500; DOI:
10.1039/P19750001500
PDF
Structure and synthesis of a new ketone from Cedrus species; some new constituents of C. atlantica Manet
David R. Adams Surendra P. Bhatnagar and Richard C. Cookson
pg 1502; DOI:
10.1039/P19750001502
PDF
1,3-Dipolar character of six-membered aromatic rings. Part X. Pyridazine and benzopyridazine betaines
Nicholas Dennis Alan R. Katritzky and Muthyala Ramaiah
pg 1506; DOI:
10.1039/P19750001506
PDF
The 13C nuclear magnetic resonance spectra of some gibberellins
Roger Evans James R. Hanson and Michael Siverns
pg 1514; DOI:
10.1039/P19750001514
PDF
Formation and reactions of ethyl 2,2-dimethyl-7-oxo-4-oxa-1-azabicyclo[3.2.0]heptane-6-carboxylate, a penam analogue
Bernard T. Golding and David R. Hall
pg 1517; DOI:
10.1039/P19750001517
PDF
Synthesis of 3-O-[6-O-(-D-galactopyranosyl)--D-galactopyranosyl]-1,2-di-O-stearoyl-L-glycerol, a digalactosyl diglyceride
Patricia A. Gent and Roy Gigg
pg 1521; DOI:
10.1039/P19750001521
PDF

Issue 16


Contents pages

pg P035; DOI:
10.1039/P197500FP035
PDF
Stereospecific syntheses of (Z)- and (E)-4-bromomethylene-5,5-dimethyl-3-phenyloxazolidin-2-one
Christopher C. Browne and Nazim Punja
pg 1525; DOI:
10.1039/P19750001525
PDF
Solvent and ion-pair effects on the self-condensation of linear aliphatic aldehydes: selective synthesis of substituted acrylaldehydes and glycol monoesters
Giuseppe Casnati Andrea Pochini Giuseppe Salerno and Rocco Ungaro
pg 1527; DOI:
10.1039/P19750001527
PDF
Opium alkaloids. Part XVI. The biosynthesis of 1-benzylisoquinolines in Papaver somniferum. Preferred and secondary pathways; stereochemical aspects
Einar Brochmann-Hanssen Chung-hsiung Chen C. Rolland Chen Hsüch-ching Chiang Albert Y. Leung and Kenneth McMurtrey
pg 1531; DOI:
10.1039/P19750001531
PDF
Lewis acid-catalysed cyclisations of 1-anthryl styryl ketone; benz[de]-anthracen-3-one
Hugh J. Williams and Richard L. Harlow
pg 1537; DOI:
10.1039/P19750001537
PDF
Chemical investigation of Ceylonese plants. Part XV. Extractives of Kayea stylosa Thw. (Guttiferae)
Sarath P. Gunasekera Sathiadevan Selliah and M.Uvais S. Sultanbawa
pg 1539; DOI:
10.1039/P19750001539
PDF
Overcrowded molecules. Part XI. A doubly forbidden symmetry-allowed pericyclic reaction: the thermal rearrangement of (E)-2-benzylidene-(Z)-1-mesityl(phenyl)methyleneindane into (Z)-2-benzyl-1-mesityl(phenyl)methyleneindene
John S. Hastings Harry G. Heller Howard Tucker and Keith Smith
pg 1545; DOI:
10.1039/P19750001545
PDF
Biosynthesis of phenylpropanoid compounds. Part II. Incorporation of specifically labelled cinnamic acids into eugenol
Paolo Manitto Paola Gramatica and Diego Monti
pg 1548; DOI:
10.1039/P19750001548
PDF
Microbiological hydroxylation. Part XIX. The action of an ant fungus (Acromyrmex fungus) on oxygenated androstanes, pregnanes, and cholestanes
Sir Ewart R. H. Jones G. Denis Meakins John O. Miners John H. Pragnell and Alistair L. Wilkins
pg 1552; DOI:
10.1039/P19750001552
PDF
Reaction of 3-methylindole with a diazonium salt
Malcolm F. G. Stevens
pg 1555; DOI:
10.1039/P19750001555
PDF
Formation of Meisenheimer–Jackson complexes in a non-polar solvent
Anthony R. Butler
pg 1557; DOI:
10.1039/P19750001557
PDF
A cis-perhydroindanone synthesis utilising an intramolecular Diels–Alder reaction
Jan J. S. Bajorek and James K. Sutherland
pg 1559; DOI:
10.1039/P19750001559
PDF
Structures of three new steroidal sapogenins from Dioscorea prazeri
Krishnamurthy Rajaraman Ashok Kumar Batta and Srinivasa Rangaswami
pg 1560; DOI:
10.1039/P19750001560
PDF
Application of a lanthanide shift reagent, Eu(fod)3 to the elucidation of the structures of flavones and related compounds
Masayoshi Okigawa Nizam U. Khan Nobusuke Kawano and Wasiur Rahman
pg 1563; DOI:
10.1039/P19750001563
PDF
Synthesis and chemistry of S-acylthiol S-oxides and related compounds
Derek H. R. Barton David P. Manly and David A. Widdowson
pg 1568; DOI:
10.1039/P19750001568
PDF
A new method for the deoxygenation of secondary alcohols
Derek H. R. Barton and Stuart W. McCombie
pg 1574; DOI:
10.1039/P19750001574
PDF
Cyclonerotriol [6-(3-hydroxy-2,3-dimethylcyclopentyl)-2-methylhept-2-ene-1,6-diol], a new sesquiterpenoid metabolite of Fusarium culmorum
James R. Hanson Peter B. Hitchcock and Robert Nyfeler
pg 1586; DOI:
10.1039/P19750001586
PDF
Photodecomposition of acetoins
Hong-Son Ryang and Hiroshi Sakurai
pg 1590; DOI:
10.1039/P19750001590
PDF
Electrocyclic reactions. Part VII. Irradiation of 3,5-dibromo-2,6-di-methylhepta-2,5-dien-4-one (-dibromophorone)
Charles W. Shoppee and Yueh-sha Wang
pg 1595; DOI:
10.1039/P19750001595
PDF
An improved method for the preparation of monoalkylketens
Colin C. McCarney and Robert S. Ward
pg 1600; DOI:
10.1039/P19750001600
PDF
Preparation and properties of -oxo-thionesters
Alexander J. Bridges and Gordon H. Whitham
pg 1603; DOI:
10.1039/P19750001603
PDF
Photochemistry of bromobiphenyls: steric effects and electron transfer
Nigel J. Bunce Stephen Safe and L. Octavio Ruzo
pg 1607; DOI:
10.1039/P19750001607
PDF
Experiments on the synthesis of tetracycline. Part XIII. Oxidation of ring A model phenols to p-hydroxycyclohexadienones
Derek H. R. Barton Philip D. Magnus and John C. Quinney
pg 1610; DOI:
10.1039/P19750001610
PDF
Improved methods for the oxidation of primary and secondary alcohols
Derek H. R. Barton and Craig P. Forbes
pg 1614; DOI:
10.1039/P19750001614
PDF
Unconventional nucleotide analogues. Part XIII. (2S,4S)-2-hydroxymethyl- and 2-carboxy-4-(purin-9-yl)pyrrolidines
Frans M. Kaspersen and Upendra K. Pandit
pg 1617; DOI:
10.1039/P19750001617
PDF
Biosynthesis of vitamin B6. Incorporation of glycolaldehyde into pyridoxal
Robert E. Hill Peter Horsewood Ian D. Spenser and Yoshiki Tani
pg 1622; DOI:
10.1039/P19750001622
PDF
Allenes. Part XXXII. A general synthesis of allenediynes from allenic bromides and butadiynyl(trimethyl)silane and the synthesis of two natural allenes, ()-octa-2,3-diene-5,7-diyn-1-ol and ()-undeca-5,6-diene-8,10-diyn-1-ol
Phyllis D. Landor Stephen R. Landor and Philip Leighton
pg 1628; DOI:
10.1039/P19750001628
PDF

Issue 17


Contents pages

pg P037; DOI:
10.1039/P197500FP037
PDF
Polyfluoroalkyl derivatives of nitrogen. Part XLII. Reaction of N-bromobistrifluoromethylamine with 1H-pentafluoropropene and some further studies on the thermal rearrangement of NN-bistrifluoromethyl-vinylamines
George L. Fleming Robert N. Haszeldine James R. McAllister and Anthony E. Tipping
pg 1633; DOI:
10.1039/P19750001633
PDF
Carbene chemistry. Part IX. Some C-H insertion reactions of dichlorocarbene in the gas phase
J. Michael Birchall Robert N. Haszeldine and Peter Tissington
pg 1638; DOI:
10.1039/P19750001638
PDF
Ring C functionalised diterpenoids. Part VI. Solvolysis of ent-methyl 12-p-tolylsulphonyloxybeyeran-19-oate
Alan J. McAlees Robert McCrindle and Shane T. Murphy
pg 1641; DOI:
10.1039/P19750001641
PDF
Studies on proaporphine and aporphine alkaloids. Part V. Synthesis of ()-glaziovine by 8,1-ring closure of 1-benzylisoquinoline derivatives
Cesare Casagrande and Luigi Canonica
pg 1647; DOI:
10.1039/P19750001647
PDF
Studies on proaporphine and aporphine alkaloids. Part VI. Synthesis of ()-glaziovine by spiran ring construction on a cyclopent[ij]isoquinoline; stereochemistry of reduced proaporphines
Cesare Casagrande Luigi Canonica and (Mrs.) Giuliana Severini-Ricca
pg 1652; DOI:
10.1039/P19750001652
PDF
Studies on proaporphine and aporphine alkaloids. Part VII. Stereochemistry of reduced proaporphines of Croton sparsiflorus and C. linearis
Cesare Casagrande Luigi Canonica and (Mrs.) Giuliana Severini-Ricca
pg 1659; DOI:
10.1039/P19750001659
PDF
Intramolecular catalysis. Part II. Electrophilic anchimeric assistance by a hydroxy-group in the opening of steroidal epoxides by azide anions
Yoram Houminer
pg 1663; DOI:
10.1039/P19750001663
PDF
Synthesis of 1-aryloxymethyl- and 1-arylthiomethyl-imidazoles
Keith H. Baggaley Stanley G. Brooks and Richard M. Hindley
pg 1670; DOI:
10.1039/P19750001670
PDF
Oxidation of 2-hydroxy--phenylchalcones: substituent effects on the course of the Algar–Flynn–Oyamada (AFO) reaction
William P. Cullen Dervilla M. X. Donnelly Alan K. Keenan Patrick J. Keenan and K. Ramdas
pg 1671; DOI:
10.1039/P19750001671
PDF
Chemistry of ultrasound. Part IV. Effects of ultrasound on some amino-acids
William H. Staas and Langley A. Spurlock
pg 1675; DOI:
10.1039/P19750001675
PDF
Preparation and reactions of some o-dialkylaminoarylmethylene-substituted azlactones (oxazol-5-ones)
Krzysztof B. Niewiadomski and Hans Suschitzky
pg 1679; DOI:
10.1039/P19750001679
PDF
The structures of D-arabinose and D-glucose oximes
Paul Finch and Z. Merchant
pg 1682; DOI:
10.1039/P19750001682
PDF
Condensed thiophen ring systems. Part XVIII. Thienoazepines and thienobenzoxazoles from 6-azidobenzo[b]thiophens
Brian Iddon Michael W. Pickering Hans Suschitzky and David S. Taylor
pg 1686; DOI:
10.1039/P19750001686
PDF
Synthesis of [1-(L- and [1-(D-2-hydroxy-3-mercaptopropanoic acid)-8-lysine]-vasopressin
Manfred Wälti and Derek B. Hope
pg 1691; DOI:
10.1039/P19750001691
PDF
The photochemistry of carbohydrate derivatives. Part III. Photochemical rearrangements of 2,3- and 3,4-O-o-nitrobenzylideneglycopyranosides
Peter M. Collins and Nathan N. Oparaeche
pg 1695; DOI:
10.1039/P19750001695
PDF
The photochemistry of carbohydrate derivatives. Part IV. Photochemical rearrangement of 4,6-O-o-nitrobenzylideneglycopyranosides
Peter M. Collins Nathan N. Oparaeche and V. Ranjit N. Munasinghe
pg 1700; DOI:
10.1039/P19750001700
PDF
3-Hydroxymethylenechroman-4-one
Francis M. Dean and Stephen Murray
pg 1706; DOI:
10.1039/P19750001706
PDF
Polypeptides. Part XIII. Preparation of -aza-amino-acid (carbazic acid) derivatives and intermediates for the preparation of -aza-peptides
Anand S. Dutta and John S. Morley
pg 1712; DOI:
10.1039/P19750001712
PDF
Photocyclisation of enamides. Part VII. A new synthesis of the protoberberine alkaloids
Ichiya Ninomiya Takeaki Naito and Hisashi Takasugi
pg 1720; DOI:
10.1039/P19750001720
PDF
Type II photoelimination of thiobenzoic acid O-esters; photolysis of optically active O-2-phenylbutyl thiobenzoate
Yoshiro Ogata Katsuhiko Takagi and Shigenori Ihda
pg 1725; DOI:
10.1039/P19750001725
PDF
Synthesis of -damascone [trans-1-(2,6,6-trimethylcyclohex-3-enyl)but-2-en-1-one] and -damascenone [trans-1-(2,6,6-trimethylcyclohexa-1,3-dienyl)but-2-en-1-one]
K. Subrahmania Ayyar Richard C. Cookson and Douglas A. Kagi
pg 1727; DOI:
10.1039/P19750001727
PDF
Synthesis and structure of edulans I and II
David R. Adams Surendra P. Bhatnagar and Richard C. Cookson
pg 1736; DOI:
10.1039/P19750001736
PDF

Issue 18


Contents pages

pg P039; DOI:
10.1039/P197500FP039
PDF
Simple syntheses of the atlantones, the ocimenones, the tagetones, and filifolone from isoprene
David R. Adams Surendra P. Bhatnagar Richard C. Cookson and Robert M. Tuddenham
pg 1741; DOI:
10.1039/P19750001741
PDF
Formimidoyl cyanide and isocyanide from azidoacetonitrile by photolysis
Joseph H. Boyer Jonathan Dunn and Johannes Kooi
pg 1743; DOI:
10.1039/P19750001743
PDF
Benzonitrile N-(phthalimido)imide, a functionalised 1,3-dipole. Preparation of 4,5,8-triphenylpyridazino[4,5-d]triazine and generation of 3,6-diphenyl-4,5-didehydropyridazine
Thomas L. Gilchrist Geoffrey E. Gymer and Charles W. Rees
pg 1747; DOI:
10.1039/P19750001747
PDF
Marine steroids. Part II. A synthesis of 3,6-dihydroxy-5-pregn-9(11)-en-20-one
Derek S. H. Smith and Alan B. Turner
pg 1751; DOI:
10.1039/P19750001751
PDF
Nitroxide radicals. Part XVII. Transannular interactions in [2.2]paracyclophanyl nitroxides
Alexander R. Forrester and Rene Ramasseul
pg 1753; DOI:
10.1039/P19750001753
PDF
The structures of three new meliacins isolated from Khaya anthotheca heartwood
Thomas G. Halsall and Jeffrey A. Troke
pg 1758; DOI:
10.1039/P19750001758
PDF
A new rearrangement of ketonic nitrones; a convenient alternative to the Beckmann rearrangement
Derek H. R. Barton Michael J. Day Robert H. Hesse and Maurice M. Pechet
pg 1764; DOI:
10.1039/P19750001764
PDF
Electrophilic bromination of bicyclo[3.2.0]hept-2-en-6-ones
Zdzislaw Grudzinski and Stanley M. Roberts
pg 1767; DOI:
10.1039/P19750001767
PDF
The reaction of diol thiocarbonates with methyl iodide: a synthesis of 6-deoxy-sugars
Derek H. R. Barton and Robert V. Stick
pg 1773; DOI:
10.1039/P19750001773
PDF
Isolation of 5,7-dihydroxy-2-methylchromone and its 7-O-glycosides from Adina rubescens
Richard T. Brown Walter P. Blackstock and C. Lyn Chapple
pg 1776; DOI:
10.1039/P19750001776
PDF
Synthesis of 3-O-{6-O-[6-O-(-D-galactopyranosyl)--D-galactopyranosyl]--D-galactopyranosyl}-1,2-di-O-stearoyl-L-glycerol, a trigalactosyl diglyceride
Patrica A. Gent and Roy Gigg
pg 1779; DOI:
10.1039/P19750001779
PDF
Heterocyclic compounds from urea derivatives. Part XXII. Thiobenzoylated carbonohydrazides and their cyclisation
Roshan Esmail and Frederick Kurzer
pg 1781; DOI:
10.1039/P19750001781
PDF
Heterocyclic compounds from urea derivatives. Part XXIII. Thiobenzoylated thiocarbonohydrazides and their cyclisation
Roshan Esmail and Frederick Kurzer
pg 1787; DOI:
10.1039/P19750001787
PDF
Photocyclisation of enamides. Part VIII. Synthesis of 13-methylberbines; total synthesis of ()-cavidine
Ichiya Ninomiya Takeaki Naito and Hisashi Takasugi
pg 1791; DOI:
10.1039/P19750001791
PDF
Alkyl metal asymmetric reduction. Part VIII. Stereoselectivity of the reduction of alkyl phenyl ketones by optically active aliphatic Grignard reagents
Giampaolo Giacomelli Luciano Lardicci and Anna M. Caporusso
pg 1795; DOI:
10.1039/P19750001795
PDF
Unconventional nucleotide analogues. Part XIV. (2S,4S)-2-Hydroxy-methyl- and 2-carboxy-4-(pyrimidin-1-yl)pyrrolidines
Frans M. Kaspersen and Upendra K. Pandit
pg 1798; DOI:
10.1039/P19750001798
PDF
Preparation and some reactions of 2,2-diaryl-2H-imidazole 1-oxides
Bernard A. J. Clark Timothy J. Evans and Robin G. Simmonds
pg 1803; DOI:
10.1039/P19750001803
PDF
Photolysis of N-arylsulphonyl-SS-dimethylsulphoximides in aromatic solvents. Photoisomerisation of methylbiphenyls
Rudolph A. Abramovitch and Takao Takaya
pg 1806; DOI:
10.1039/P19750001806
PDF
Rationalisation of cycloaddition behaviour by use of Hckel frontier molecular orbitals
King-Leung Mok and Martin J. Nye
pg 1810; DOI:
10.1039/P19750001810
PDF
Displacement of the hydroxy-group from ferrocenylmethanol by amines
Athelstan L. J. Beckwith and Graham G. Vickery
pg 1818; DOI:
10.1039/P19750001818
PDF
Studies on the syntheses of heterocyclic compounds. Part DCXX. Total synthesis of ()-orientalidine and a positional isomer
Tetsuji Kametani Akira Ujiie Masataka Ihara and Keiichiro Fukumoto
pg 1822; DOI:
10.1039/P19750001822
PDF
Studies on the syntheses of heterocyclic compounds. Part DCXXII. Total synthesis of ()-mappicine [7-(1-hydroxypropyl)-8-methyl-indolizino[1,2-b]quinolin-9(11H)-one]
Tetsuji Kametani Hiromitsu Takeda Hideo Nemoto and Keiichiro Fukumoto
pg 1825; DOI:
10.1039/P19750001825
PDF
Axial preference of a 2-anilino-substituent in 4-methyl-1,3,2-dioxaphosphorinan
Wojciech J. Stec and Andrzej Okruszek
pg 1828; DOI:
10.1039/P19750001828
PDF

Issue 19


Contents pages

pg P041; DOI:
10.1039/P197500FP041
PDF
Rearranged sterenes in a shale: occurrence and simulated formation
Ian Rubinstein Odette Sieskind and Pierre Albrecht
pg 1833; DOI:
10.1039/P19750001833
PDF
Rearrangements and cyclization of -alkoxyalkyl- and -phenoxyalkyl-carbamoyl chlorides
Raymond Banks Robert F. Brookes and David H. Godson
pg 1836; DOI:
10.1039/P19750001836
PDF
Condensation between 2-chloro-3H-indol-3-one and phenols
William J. Begley and James Grimshaw
pg 1840; DOI:
10.1039/P19750001840
PDF
Photochemical reactions. Part V. Photoinduced cyclisations of 3-aroylchromones
Peter G. Sammes and Timothy W. Wallace
pg 1845; DOI:
10.1039/P19750001845
PDF
Polycyclic fused amidines. Part I. Imidazo- and pyrimido-[1,2-f]-phenanthridines
Ronald F. Cookson and Ronald E. Rodway
pg 1850; DOI:
10.1039/P19750001850
PDF
Polycyclic fused amidines. Part II. Synthesis of dihydroimidazo-fused systems by use of 2-aminoethylammonium toluene-p-sulphonate
Ronald F. Cookson and Ronald E. Rodway
pg 1854; DOI:
10.1039/P19750001854
PDF
Reaction of 6-amino-1,3-dimethyl-5-nitrosouracil with thiols
Raymond D. Youssefyeh
pg 1857; DOI:
10.1039/P19750001857
PDF
Synthesis of 18-substituted steroids. Part I. 18,21-Dihydroxypregn-4-ene-3,20-dione (18-hydroxydeoxycorticosterone)
David N. Kirk and Maruthiandan S. Rajagopalan
pg 1860; DOI:
10.1039/P19750001860
PDF
Absolute configuration of the most potent isomer of the pyrethroid insecticide -cyano-3-phenoxybenzyl cis-3-(2,2-dibromovinyl)-2,2-dimethylcyclopropanecarboxylate by crystal structure analysis
John D. Owen
pg 1865; DOI:
10.1039/P19750001865
PDF
Coumarins and related compounds. Part XXI. A reinvestigation of the reaction between 1-naphthol and 2-formyl-2-phenylacetonitrile
Arun K. Das Gupta Rabindra M. Chatterje and Sailendra N. Choudhuri
pg 1869; DOI:
10.1039/P19750001869
PDF
Cyclopropylcarbinyl–oxocarbonium ions. Part VII. Orientational effects
Bruno K. Radatus and Bert Fraser-Reid
pg 1872; DOI:
10.1039/P19750001872
PDF
Organophosphorus intermediates. Part VI. Base-catalysed reaction of methyl phosphinate with tetraphenylcyclopentadienone
Christopher J. R. Fookes and Michael J. Gallagher
pg 1876; DOI:
10.1039/P19750001876
PDF
Studies on lactams. Part XLII. A stereoselective synthesis of some -amido--lactams
Ajay K. Bose M. S. Manhas H. P. S. Chawla and B. Dayal
pg 1880; DOI:
10.1039/P19750001880
PDF
Enamine chemistry. Part XX. Reactions of -unsaturated acid chlorides. Synthesis of alkyl 2,6-dioxobicyclo[3.3.1]nonane-1-carboxylates, alkyl 2,9-dioxobicyclo[3.3.1]nonane-7-carboxylates, and 2,9-dioxobicyclo[3.3.1]nonane-7-carbonitriles
Peter W. Hickmott Kevin N. Woodward and Raymond Urbani
pg 1885; DOI:
10.1039/P19750001885
PDF
Experiments on the synthesis of pyrazine nucleosides
Gordon W. H. Cheeseman Alan J. Freestone Robert A. Godwin and Thomas L. Hough
pg 1888; DOI:
10.1039/P19750001888
PDF
Use of carbohydrate derivatives for studies of phosphorus stereochemistry. Part V. Preparation and some reactions of tetrahydro-1,3,2-oxazaphosphorine-2-ones and -2-thiones
John M. Harrison Thomas D. Inch and Gilbert J. Lewis
pg 1892; DOI:
10.1039/P19750001892
PDF
Unsaturated nitrogen compounds containing fluorine. Part VI. Reactions of hexafluoroacetone azine with 2-methylbut-2-ene, 2,3-dimethylbut-2-ene, 2,3-dimethylbut-1-ene, and cyclopentene
Stuart E. Armstrong T. Philip Forshaw and Anthony E. Tipping
pg 1902; DOI:
10.1039/P19750001902
PDF
A new synthesis of alloxazines by the reaction of diethyl azodiformate with 6-anilinouracils
Fumio Yoneda Shigeru Matsumoto Yoshiharu Sakuma and Shinobu Fukazawa
pg 1907; DOI:
10.1039/P19750001907
PDF
1H-pyrrolo[2,3-b]pyridines. Part III. A novel synthetic route from 1-substituted 2-aminopyrroles
Andrew Brodrick and D. George Wibberley
pg 1910; DOI:
10.1039/P19750001910
PDF
Formation of methyl ethers from photoaddition of methanol to phenyl-substituted butadienes
Peter J. Baldry
pg 1913; DOI:
10.1039/P19750001913
PDF
Preparation of sulphur-containing nitrones from sulphides. Thermal elimination reactions of nitrones
Wynford M. Leyshon and David A. Wilson
pg 1920; DOI:
10.1039/P19750001920
PDF
Photolysis of sulphur-containing nitrones. Support for a methyleneoxaziridine radical intermediate and formation of new heterocycles
Wynford M. Leyshon and David A. Wilson
pg 1925; DOI:
10.1039/P19750001925
PDF
A thermal reaction of 2-(thiolan-2-yl)oxaziridines and related compounds. Evidence for neighbouring group participation in the displacement of oxygen by sulphur at nitrogen
Wynford M. Leyshon and David A. Wilson
pg 1929; DOI:
10.1039/P19750001929
PDF
Formation of enantiomeric 4-oxa-2,6-diazabicyclo[3.2.0]hept-2-en-7-ones from methyl 6- and 6-phenoxyacetamidopenicillanates
Malcolm M. Campbell and Graham Johnson
pg 1932; DOI:
10.1039/P19750001932
PDF
Mode of cyclopropane ring opening of 1a,2,3,7b-tetrahydro-1-phenyl-1H-cyclopropa[a]naphthalene: a correction
Amareshwar Chatterjee Bulu Bandyopadhyay and Rita Mallik
pg 1934; DOI:
10.1039/P19750001934
PDF
Pigments of Gnomonia erythrostoma. Part III. Synthesis of a methyl ether of bisdeoxyerythrostominone
Brian E. Cross and Leslie J. Zammitt
pg 1936; DOI:
10.1039/P19750001936
PDF
Formation of oestratrienes from 5,6-epoxyandrostan-7-ols
Derek Baldwin and James R. Hanson
pg 1941; DOI:
10.1039/P19750001941
PDF
Anodic oxidation. Part XIV. Products from the electrochemical functionalisation of olefins in methanol
Roger Brettle and John R. Sutton
pg 1947; DOI:
10.1039/P19750001947
PDF
Anodic oxidation. Part XV. Electrochemical functionalisation of phenylcyclopropane and 2-isobutenyl-1,1-dimethylcyclopropane in methanol
Roger Brettle and John R. Sutton
pg 1955; DOI:
10.1039/P19750001955
PDF
13C nuclear magnetic resonance spectra of some steroidal unsaturated ketones
James R. Hanson and Michael Siverns
pg 1956; DOI:
10.1039/P19750001956
PDF
Synthesis and properties of the stereoisomeric diethyl 6-aminocyclo-hexane-1,3-dicarboxylates
Vinko kari Blanka Djuras and Vera Turjak-Zebi
pg 1959; DOI:
10.1039/P19750001959
PDF
New metabolites of Aspergillus terreus: 3-hydroxy-2,5-bis-(p-hydroxyphenyl)penta-2,4-dien-4-olide and derivatives
Bernard T. Golding Rodney W. Rickards and Zdenko Vanek
pg 1961; DOI:
10.1039/P19750001961
PDF
Photolysis and thermolysis of N-(N-arylimidoyl)sulphimides
Thomas L. Gilchrist Christopher J. Moody and Charles W. Rees
pg 1964; DOI:
10.1039/P19750001964
PDF
Reaction of N-aryl- and imidoyl-sulphimides with diphenylcyclopropenone; synthesis of 4-pyrimidones
Thomas L. Gilchrist C. John Harris Christopher J. Moody and Charles W. Rees
pg 1969; DOI:
10.1039/P19750001969
PDF
Steroids and related natural products. Part XCI. Synthesis of the cardenolides canarigenin and uzarigenin
Yoshiaki Kamano George R. Pettit and Machiko Tozawa
pg 1972; DOI:
10.1039/P19750001972
PDF
Steroids and related natural products. Part XCII. Conversion of canarigenone[14-hydroxy-3-oxo-14-carda-4,20(22)-dienolide] into periplogenin [3,5,14-trihydroxy-5,14-card-20(22)-enolide]
Yoshiaki Kamano George R. Pettit and Machiko Tozawa
pg 1976; DOI:
10.1039/P19750001976
PDF
Structure of the lichen depsidone pannarin
David A. Jackman Melvyn V. Sargent and John A. Elix
pg 1979; DOI:
10.1039/P19750001979
PDF
Structure of the lichen depsidone gangaleoidin
Melvyn V. Sargent Paul Vogel and John A. Elix
pg 1986; DOI:
10.1039/P19750001986
PDF
Structure of the lichen deposidone variolaric acid
Nicola Michael Rana Melvyn V. Sargent and John A. Elix
pg 1992; DOI:
10.1039/P19750001992
PDF
Overcrowded molecules. Part XII. Thermal and photochemical reactions of (2Z,3Z)-and (2Z,3E)-2-benzylidene-2,3-dihydro-3-mesityl(phenyl)-methylenebenzofuran
John S. Hastings Harry G. Heller and Kingsley Salisbury
pg 1995; DOI:
10.1039/P19750001995
PDF
Synthesis of 17-(2-amino-oxazol-4-yl)-steroids
Gianfranco Rapi Mauro Ginanneschi and Mario Chelli
pg 1999; DOI:
10.1039/P19750001999
PDF
Reaction of 1,2-dihydrobenzocyclobutene-1-carbonitriles with methyl acrylate as an unsymmetric dienophile
Tetsuji Kametani Yasuyuki Kato Toshio Honda and Keiichiro Fukumoto
pg 2001; DOI:
10.1039/P19750002001
PDF

Issue 20


Contents pages

pg P047; DOI:
10.1039/P197500FP047
PDF
Valence-bond isomer chemistry. Part VII. Photochemical interconversion of the perfluoroxylenes
Michael G. Barlow Robert N. Haszeldine and Melvyn J. Kershaw
pg 2005; DOI:
10.1039/P19750002005
PDF
Valence-bond isomer chemistry. Part VIII. Cycloaddition reactions of derivatives of hexafluorobicyclo[2.2.0]hexa-2,5-diene, and of hexakis(trifluoromethyl)benzvalene
Michael G. Barlow Geoffrey M. Harrison Robert N. Haszeldine Ronald Hubbard Melvyn J. Kershaw and David R. Woodward
pg 2010; DOI:
10.1039/P19750002010
PDF
Polyfluorocarbanion chemistry. Part IV. Some reactions of 2H- and 1H-pentafluoropropene with nucleophiles
Robert N. Haszeldine James R. McAllister and Anthony E. Tipping
pg 2015; DOI:
10.1039/P19750002015
PDF
Amino-acids and peptides. Part I. Esterification of the carboxy-group of penicillins and cephalosporins by hydrazone oxidation
Roy Bywood Gerard Gallagher Girijesh K. Sharma and Derek Walker
pg 2019; DOI:
10.1039/P19750002019
PDF
Oxidation of aromatic anils with lead tetra-acetate
Bruno Rindone and Carlo Scolastico
pg 2022; DOI:
10.1039/P19750002022
PDF
Cyclization of ethyl acetoacetate and substituted salicylaldehydes in the presence of ammonium acetate
Akio Sakurai and Hiroshi Midorikawa
pg 2025; DOI:
10.1039/P19750002025
PDF
Studies on the syntheses of heterocyclic compounds. Part DCXXIX. A ready synthesis of indeno[2,1-a][3]benzazepines
Tetsuji Kametani Shoji Hirata Hideo Nemoto Masataka Ihara Satoshi Hibino and Keiichiro Fukumoto
pg 2028; DOI:
10.1039/P19750002028
PDF
Amino-acids and peptides. Part II. A new method for preparing diazodiphenylmethane and related compounds
J. Robert Adamson Roy Bywood David T. Eastlick Gerard Gallagher Derek Walker and Edward M. Wilson
pg 2030; DOI:
10.1039/P19750002030
PDF
Nitroxide chemistry. Part VIII. Abstraction of allylic hydrogen from isobutene by bistrifluoromethyl nitroxide
Ronald E. Banks J. Michael Birchall Alan K. Brown Robert N. Haszeldine and Frank Moss
pg 2033; DOI:
10.1039/P19750002033
PDF
Cinnolines. Part XVI. Photochemical rearrangement of 2-alkylcinnolinium-4-olates to 3-alkyl-4(3H)-quinazolones
Donald E. Ames Sosale Chandrasekhar and Roy Simpson
pg 2035; DOI:
10.1039/P19750002035
PDF
Structural criteria for hydrazone photochromism in solution
Mona F. Zady Frank N. Bruscato and John L. Wong
pg 2036; DOI:
10.1039/P19750002036
PDF
Microbiological hydroxylation. Part XX. Hydroxylation of dioxygenated 5-androstanes with the fungi Absidia regnieri and Syncephelastrum racemosum
Alan M. Bell Sir Ewart R. H. Jones G. Denis Meakins John O. Miners and Alistair L. Wilkins
pg 2040; DOI:
10.1039/P19750002040
PDF
Saponins isolated from Bupleurum falcatum L.; components of saikosaponin b
Ariyoshi Shimaoka Shujiro Seo and Hitoshi Minato
pg 2043; DOI:
10.1039/P19750002043
PDF
Ring–chain tautomerism of some o-benzoylbenzanilides
Munir Ahmed and John M. Vernon
pg 2048; DOI:
10.1039/P19750002048
PDF
Polycyclic systems. Part XVI. Synthesis of 1-isopropyl-2,8-dimethylphenanthrene
Dhanonjoy Nasipuri and Ila De Dalal
pg 2052; DOI:
10.1039/P19750002052
PDF
New reactions of triplet oxygen which avoid the spin barrier
Derek H. R. Barton Richard K. Haynes Gérard Leclerc Phillip D. Magnus and Ian D. Menzies
pg 2055; DOI:
10.1039/P19750002055
PDF
Peroxide–diene oxygen transfer reactions induced by titanium tetrachloride
Derek H. R. Barton and Richard K. Haynes
pg 2065; DOI:
10.1039/P19750002065
PDF
The structure of daucic acid
Derek H. R. Barton Barry D. Brown Damon D. Ridley David A. Widdowson Alfred J. Keys and Christopher J. Leaver
pg 2069; DOI:
10.1039/P19750002069
PDF
Condensation of ethyl diazoacetate with cobalt porphyrins
Alan W. Johnson David Ward Peter Batten Alan L. Hamilton Geoffrey Shelton and Clive M. Elson
pg 2076; DOI:
10.1039/P19750002076
PDF
Determination of the stereochemistry of the product of rearrangement of penicillin G with methyl chloroformate by total synthesis
Christopher J. Veal and Douglas W. Young
pg 2086; DOI:
10.1039/P19750002086
PDF
Complexing of terpenes with transition metals. Part V. Reactions of 3,7-dimethylocta-1,6-diene and of 7-methoxy-3,7-dimethyloct-1-ene with rhodium(III) and thallium(III)
Francis J. McQuillin and David George Parker
pg 2092; DOI:
10.1039/P19750002092
PDF

Issue 21


Contents pages

pg P049; DOI:
10.1039/P197500FP049
PDF
Studies of heterocyclic compounds. Part XVIII. Protonation of 1,6-dioxa-6a-thia- and 1,6-dioxa-6a-selena-pentalenes: formation of 1,2-oxathiolium and 1,2-oxaselenolium cations
David H. Reid and Robert G. Webster
pg 2097; DOI:
10.1039/P19750002097
PDF
Pyrylium salts. Part VI. Derivatives of 3,11-dithiatricyclo[5.3.1.12,6]-dodecane by dimerisation of thiopyrylium-3-olates
Sigurd Baklien Per Groth and Kjell Undheim
pg 2099; DOI:
10.1039/P19750002099
PDF
Studies on the syntheses of heterocyclic compounds. Part CDXXXIV. A novel total synthesis of olivacine (1,5-dimethyl-6H-pyrido[4,3-b]-carbazole)
Tetsuji Kametani Toshio Suzuki Yoshifumi Ichikawa and Keiichiro Fukumoto
pg 2102; DOI:
10.1039/P19750002102
PDF
Conformational aspects of some 5-methyl-19-nor-steroids
Erwin Glotter Yechiel Rabinsohn and Yehuda Ozari
pg 2104; DOI:
10.1039/P19750002104
PDF
Structural studies on the antibiotic vancomycin: evidence for the presence of modified phenylglycine and -hydroxytyrosine units
Gerald A. Smith Kenneth A. Smith and Dudley H. Williams
pg 2108; DOI:
10.1039/P19750002108
PDF
Determination of the substitution pattern of an isoxazole by 13C nuclear magnetic resonance
Gavin M. Buchan and Alan B. Turner
pg 2115; DOI:
10.1039/P19750002115
PDF
The meliacins (limonoids): minor constituents of Khaya anthotheca: reduction of the meliacins with zinc–copper couple
Donald E. U. Ekong Joseph I. Okogun and B. Lucas Sondengam
pg 2118; DOI:
10.1039/P19750002118
PDF
Structure of aromatic diazocyanides; synthesis of diazoisocyanides
Teresa Ignasiak (the late) Jerzy Suszko and Boleslow Ignasiak
pg 2122; DOI:
10.1039/P19750002122
PDF
Formation of vinyl sulphides via successive sigmatropic rearrangements of an allylic sulphonium ylide
A. Johan H. Labuschagne Cornelius J. Meyer Hendrik S. C. Spies and David F. Schneider
pg 2129; DOI:
10.1039/P19750002129
PDF
Absolute configuration of ancistrocladisine and ancistrocladidine
Tuticorin R. Govindachari Papagudi C. Parthasarathy Tuticorin G. Rajagopalan Haridutt K. Desai Kalpathi S. Ramachandran and Eun Lee
pg 2134; DOI:
10.1039/P19750002134
PDF
Withanolides Q and R, two new 23-hydroxy-steroidal lactones
Isaac Kirson Ariela Cohen and Arieh Abraham
pg 2136; DOI:
10.1039/P19750002136
PDF
Studies on 7-(3,5-dideoxy-2-C-methoxycarbonyl--L-pentofuranosyl)-theophyllines. Configuration at the branch point and biological activity
Therese Halmos and Kostas Antonakis
pg 2138; DOI:
10.1039/P19750002138
PDF
On stereochemical preference in the SE2 reaction
Ian M. Cunningham and Karl H. Overton
pg 2140; DOI:
10.1039/P19750002140
PDF
Synthesis of compounds related to gibberellic acid. Part IV. Construction of a tetracyclic system containing functional elements of rings A, C, and D
H. J. Eli Loewenthal and Shimon Schatzmiller
pg 2149; DOI:
10.1039/P19750002149
PDF
[A-21-D-Asparagine] sheep insulin, a diastereoisomer of the natural hormone
Alexandros Cosmatos Stanley Johnson Benjamin Breier and Panayotis G. Katsoyannis
pg 2157; DOI:
10.1039/P19750002157
PDF
Arylazo-glycenosides. Part IV. Synthesis and reactions of some 2- and 3-arylazo-derivatives of methyl 2,3-dideoxy-D-pent-2-enofuranoside
Peter M. Collins John R. Hurford and W. George Overend
pg 2163; DOI:
10.1039/P19750002163
PDF
Arylazo-glycenosides. Part V. Cycloadditions with methyl 5-O-benzoyl-2,3-dideoxy-3-phenylazo-- and --D-glycero-pent-2-enofuranoside
Peter M. Collins John R. Hurford and W. George Overend
pg 2178; DOI:
10.1039/P19750002178
PDF
The Dimroth rearrangement. Part XVIII. Syntheses and rearrangement of 4-iminoquinazolines and related systems
Desmond J. Brown and Kazuharu Ienaga
pg 2182; DOI:
10.1039/P19750002182
PDF
Reactions of quinones with aromatic ethers. Part VII. Triphenylene-1,4 : 5,8-diquinones from reactions of veratrole or 3,4-dimethoxyphenylbenzoquinones with benzoquinones
Robert Buchan and Oliver C. Musgrave
pg 2185; DOI:
10.1039/P19750002185
PDF
Synthesis and reactivity of 3-methylisoxazolo[4,5-c]pyridines
Giorgio Adembri Alfredo Camparini Fabio Ponticelli and Piero Tedeschi
pg 2190; DOI:
10.1039/P19750002190
PDF
Carotenoids and related compounds. Part XXXII. Synthesis of astaxanthin, phoenicoxanthin, hydroxyechinenone, and the corresponding diosphenols
Robin D. G. Cooper John B. Davis Allan P. Leftwick Colin Price and Basil C. L. Weedon
pg 2195; DOI:
10.1039/P19750002195
PDF

Issue 22


Contents pages

pg P051; DOI:
10.1039/P197500FP051
PDF
Steroids and Walden inversion. Part LXX. Re-examination of the substitution reactions of 5-cholestan-6-ol
Charles W. Shoppee and Robert D. Lundberg
pg 2205; DOI:
10.1039/P19750002205
PDF
Steroids. Part XXXVIII. 5-Chloro-5-cholestane
Charles W. Shoppee and Robert D. Lundberg
pg 2208; DOI:
10.1039/P19750002208
PDF
Electrocyclic reactions. Part VIII. Some reactions of trans,trans- and cis,trans-2-bromo-1,5-diphenylpenta-1,4-dien-3-one (-bromodibenzylideneacetone)
Charles W. Shoppee and Burgess J. A. Cooke
pg 2210; DOI:
10.1039/P19750002210
PDF
Chemical investigation of ceylonese plants. Part XVI. Extractives of Calophyllum cordato-oblongum Thw. (Guttiferae)
Sarath P. Gunasekera and M. Uvais S. Sultanbawa
pg 2215; DOI:
10.1039/P19750002215
PDF
Photochemical reactions of aromatic compounds. Part XXIII. Photochemical reactions of alkyl vinyl ethers with 2-naphthonitrile
Kazuhiko Mizuno Chyongjin Pac and Hiroshi Sakurai
pg 2221; DOI:
10.1039/P19750002221
PDF
Overcrowded molecules. Part XIII. Thermally stable photochromic systems involving (E)-2-isopropylidene-3-(naphthylmethylene)succinic anhydrides and N-phenylimides
Robert J. Hart Harry G. Heller Robert M. Megit and Mark Szewczyk
pg 2227; DOI:
10.1039/P19750002227
PDF
The chemistry of terpenes. Part XX. Autoxidation of (+)-car-3-ene
David A. Baines and Wesley Cocker
pg 2232; DOI:
10.1039/P19750002232
PDF
Stereochemistry of addition of fluorine to olefins by cobalt trifluoride
Angelo Bergomi and James Burdon
pg 2237; DOI:
10.1039/P19750002237
PDF
Isomer ratios from the bromination of allyl chloride in water, methanol, acetic acid, and trifluoroacetic acid
D. Lyn H. Williams
pg 2238; DOI:
10.1039/P19750002238
PDF
Purine studies. Part XV. Addition of hydrogen sulphite ion to purines
William Pendergast
pg 2240; DOI:
10.1039/P19750002240
PDF
Improved syntheses of aldosterone
Derek H. R. Barton Nilaj K. Basu Michael J. Day Robert H. Hesse Maurice M. Pechet and Alvin N. Starratt
pg 2243; DOI:
10.1039/P19750002243
PDF
Synthesis of 11-deoxy-18-hydroxycorticosterone and 18-hydroxycorticosterone 21-acetates
Derek H. R. Barton Michael J. Day Robert H. Hesse and Maurice M. Pechet
pg 2252; DOI:
10.1039/P19750002252
PDF
Quinone methides derived from Uhl's ketone
Gavin M. Buchan and Alan B. Turner
pg 2257; DOI:
10.1039/P19750002257
PDF
Reaction of acidified nitrite solutions with peptide derivatives: evidence for nitrosamine and thionitrite formation from 15N N.m.r. Studies
Raymond Bonnett Robin Holleyhead Brian L. Johnson and Edward W. Randall
pg 2261; DOI:
10.1039/P19750002261
PDF
trans-Cycloalkenes. Part V. 1-Methyl-trans-cyclo-octene
Alexander J. Bridges and Gordon H. Whitham
pg 2264; DOI:
10.1039/P19750002264
PDF
trans-Cycloalkenes. Part VI. Addition of iodine(I) azide to trans-cyclo-octene
Rodney C. Hayward and Gordon H. Whitham
pg 2267; DOI:
10.1039/P19750002267
PDF
Reactions of heterocycles with thiophosgene. Part V. 7-Chloro-1,2-dihydro-4-methoxy-2-thioxoquinoline-3-carbaldehyde, a product from 7-chloro-4-methoxyquinoline
Roy Hull Mrs. Patricia J. van den Broek and Michael L. Swain
pg 2271; DOI:
10.1039/P19750002271
PDF
Formation of 1,2,4-triazoles from the reactions of N-arylmandelamidrazones with aldehydes and with trialkyl ortho esters
John K. Fraser Douglas G. Neilson Leslie R. Newlands Kathleen M. Watson and Mohammed I. Butt
pg 2280; DOI:
10.1039/P19750002280
PDF
Backbone rearrangements of steroidal 5-enes
David N. Kirk and Philip M. Shaw
pg 2284; DOI:
10.1039/P19750002284
PDF
Synthetic studies of withanolides. Part I. Synthesis of 5,6-epoxy-4-hydroxy-5-cholest-2-en-1-one and related compounds
Masaji Ishiguro Akira Kajikawa Toshio Haruyama Yoshiko Ogura Mari Okubayashi Masuo Morisaki and Nobuo Ikekawa
pg 2295; DOI:
10.1039/P19750002295
PDF
Studies on steroids. Part XXIX. Synthesis of allenic analogues of fucosterol and desmosterol
Yoshinori Fujimoto Masuo Morisaki and Nobuo Ikekawa
pg 2302; DOI:
10.1039/P19750002302
PDF
Microbiological hydroxylation. Part XXI. Hydroxylations of 3-halogeno-17-oxo-, 3-halogeno-7-oxo-, and 17-halogeno-3-oxo-androstanes by the fungi Calonectria decora, Rhizopus nigricans, and Aspergillus ochraceus
Sir Ewart R. H. Jones G. Denis Meakins John O. Miners and Alistair L. Wilkins
pg 2308; DOI:
10.1039/P19750002308
PDF
The circular dichroism of N-thiobenzoyl-L--amino-acids. Part VI. Assessment of the resolution of amino-acids as their N-thiobenzoyl derivatives
Graham C. Barrett and Peter R. Cousins
pg 2313; DOI:
10.1039/P19750002313
PDF
Studies on heterocyclic compounds. Part XVI. Crystal and molecular structures of three products of 1,4-dipolar cycloaddition of dimethyl acetylenedicarboxylate to benzothiazole
Haruo Ogura Katsuko Kikuchi Hiroaki Takayanagi Kimio Furuhata Yoichi Iitaka and R. Morrin Acheson
pg 2316; DOI:
10.1039/P19750002316
PDF
Addition reactions of heterocyclic compounds. Part LXII. A new rearrangement in the quinazoline series
Patrick J. Abbott R. Morrin Acheson Mikhail Y. Kornilov and J. K. Stubbs
pg 2322; DOI:
10.1039/P19750002322
PDF
Medium-ring 1,5-dienes. Part II. The radical and electrophile-induced cyclisation of germacra-1(10),4,7(11)-triene
Edward D. Brown Teng W. Sam James K. Sutherland and Alberto Torre
pg 2326; DOI:
10.1039/P19750002326
PDF
Medium-ring 1,5-dienes. Part III. Cyclisation of germacra-1(10),4,7-(11)-triene oxides
Edward D. Brown James K. Sutherland and Teng W. Sam
pg 2332; DOI:
10.1039/P19750002332
PDF
Medium-ring 1,5-dienes. Part IV. Reactions of germacra-1(10),4,7(11)-triene with singlet oxygen and with the triphenyl phosphite–ozone adduct
Teng W. Sam and James K. Sutherland
pg 2336; DOI:
10.1039/P19750002336
PDF
Intramolecular cyclisation of phenolic oximes. Part I. Cyclisations with manganese(III) tris(acetylacetonate)
Alexander R. Forrester Ronald H. Thomson and Soo-On Woo
pg 2340; DOI:
10.1039/P19750002340
PDF
Intramolecular cyclisation of phenolic oximes. Part II. Cyclisations with brominating agents
Alexander R. Forrester Ronald H. Thomson and Soo-On Woo
pg 2348; DOI:
10.1039/P19750002348
PDF
Synthesis and reactions of 2-methyl-3-methylamino-2-azabicyclo[3.2.1]-oct-6-ene and its valence isomer
Paul Barraclough and Douglas W. Young
pg 2354; DOI:
10.1039/P19750002354
PDF
Confirmation of the site of nitrosation in tryptophan derivatives by -chymotrypsin
Thomas B. Brown and Malcolm F. G. Stevens
pg 2357; DOI:
10.1039/P19750002357
PDF
Structure of the chromotropic dimers produced from 2-arylphenanthro-[9,10-d]imidazoles
Yoshiko Sakaino Hiroshi Kakisawa and Takenori Kusumi
pg 2361; DOI:
10.1039/P19750002361
PDF
Further rearrangements of cyclopropyl epoxides. Formation of cyclobutanes and cyclobutenes
John A. Donnelly and James G. Hoey
pg 2364; DOI:
10.1039/P19750002364
PDF
Formation of carbocations from bornan-2-exo-ol and its derivatives and their reactions with some nucleophiles
Nobuhisa Kitagawa Masatomo Nojima and Niichiro Tokura
pg 2369; DOI:
10.1039/P19750002369
PDF
Synthesis of 1-hydroxycorticosterone
David E. Kime
pg 2371; DOI:
10.1039/P19750002371
PDF
Photolysis of benzoyl cyanide in solution
Johannes Kooi and Joseph H. Boyer
pg 2374; DOI:
10.1039/P19750002374
PDF
Reduction of nitro- and nitroso-compounds by tervalent phosphorus reagents. Part XII. Conversion of aryl 2-nitroaryl ethers into novel 3-aryl-2,3-dihydro-1,3,2-benzoxazaphosph(V)oles (oxazaphosphoranes) and their 2-oxo-derivatives
J. I. G. Cadogan David S. B. Grace Peter K. K. Lim and Brian S. Tait
pg 2376; DOI:
10.1039/P19750002376
PDF
Reduction of nitro- and nitroso-compounds by tervalent phosphorus reagents. Part XIII. 1H Nuclear magnetic resonance studies of 3-aryl-2,3-dihydro-1,3,2-benzoxazaphosph(V)oles and their 2-oxoanalogues
J. I. G. Cadogan David S. B. Grace and Brian S. Tait
pg 2386; DOI:
10.1039/P19750002386
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Reduction of nitro- and nitroso-compounds by tervalent phosphorus reagents. Part XIV. X-Ray crystallographic determination of the structures of 3-(2,6-dimethylphenyl)-2,3-dihydro-2,2,2-trimethoxy-1,3,2-benzoxazaphosph(V)ole and its 2-hydroxy-2-oxo-analogue
J. I. G. Cadogan Robert O. Gould Sheila E. B. Gould Patricia A. Sadler Susan J. Swire and Brian S. Tait
pg 2392; DOI:
10.1039/P19750002392
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Reduction of nitro- and nitroso-compounds by tervalent phosphorus reagents. Part XV. Reactions of certain aryl 2-nitrophenyl sulphides and their 2-azido-analogues leading to evidence for the intermediacy of 2,3-dihydro-1,3,2-benzothiazaphosph(V)oles (thiazaphosphoranes) and to the formation of dihydrodimethylphenothiazinones and pyrimido- and pyrido-[1,2-b]indazoles
J. I. G. Cadogan and Brian S. Tait
pg 2396; DOI:
10.1039/P19750002396
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Synthesis of 3,7-dimethyl-1,9-dioxo-1H,9H,10H-pyrano[3,2-c:5,6-c]dipyran-10-ylacetic acid and its ethyl ester
S. F. Tan and T. H. Tjia
pg 2405; DOI:
10.1039/P19750002405
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Issue 23


Contents pages

pg P055; DOI:
10.1039/P197500FP055
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Synthesis of heterocyclic compounds. Part XXX. Reactions of o-alkylamino- and o-dialkylamino-anilines with some -unsaturated carbonyl compounds
Hans Suschitzky Basil J. Wakefield and Roger A. Whittaker
pg 2409; DOI:
10.1039/P19750002409
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Synthesis and decomposition of some sulphamoyl azides
Rudolph A. Abramovitch and Koichi Miyashita
pg 2413; DOI:
10.1039/P19750002413
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Reactions of cytosine and cytidine with O-substituted hydroxylamines
Peter M. Schalke and C. Dennis Hall
pg 2417; DOI:
10.1039/P19750002417
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Preparation of medium-sized ring trans-cycloalkene derivatives from halogenocyclopropane intermediates by silver perchlorate-promoted solvolysis
Colin B. Reese and Andrew Shaw
pg 2422; DOI:
10.1039/P19750002422
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Synthesis of 3-alkyl-1-aryl-6,7-dihydro-6,6-dimethylindazol-4(5H)-ones, 2,3-diaryl-4,5,6,7-tetrahydroindazoles, and related compounds
Arthur J. Nunn and Frederick J. Rowell
pg 2435; DOI:
10.1039/P19750002435
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Condensed cyclic and bridged-ring systems. Part III. Regioselectivity and stereoselectivity in the acid-catalysed cyclisations of substituted benzylcyclohexanols. Stereocontrolled synthesis of some gem-carboxy–methyl-substituted hexahydrofluorene and hexahydro-5,9-methanobenzocyclo-octene derivatives
Usha R. Ghatak Jyotirmoy Chakravarty Rupak Dasgupta and Prabir C. Chakraborti
pg 2438; DOI:
10.1039/P19750002438
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Synthesis of NN-diaryltoluene-4-sulphonamides
Ian G. C. Coutts and Michael Hamblin
pg 2445; DOI:
10.1039/P19750002445
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Chemical investigation of ceylonese plants. Part XVII. Isolation and structures of the xanthones in the extractives of Mesua ferrea L. (form M. salicina Pl. and Tr.)(Guttiferae)
Sarath P. Gunasekera Samyiyah Ramachandran Sathiadevan Selliah and M. Uvais S. Sultanbawa
pg 2447; DOI:
10.1039/P19750002447
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Polyfluoroarenes. Part XXI. Synthesis, decarbonylation, and dehydration of 2,3,4,5,6-pentafluoroformanilide: formation of pentafluoro-phenyl isocyanide
Ronald E. Banks Robert N. Haszeldine and Bryan G. Willoughby
pg 2451; DOI:
10.1039/P19750002451
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Solanum alkaloids. Part XVII. The sugar unit of solamargine
(the late) Lindsay H. Briggs Richard C. Cambie and Derek M. Hyslop
pg 2455; DOI:
10.1039/P19750002455
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Synthesis of fluorinated branched-chain sugars
Karl Bischofberger Abraham J. Brink and Amor Jordaan
pg 2457; DOI:
10.1039/P19750002457
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Reaction of diazocyclopropane with steroidal 16-bromo-17-ketones
Duncan R. Rae
pg 2460; DOI:
10.1039/P19750002460
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Neighbouring-group effects in the oxidation of olefins by mercury(II), thallium(III), and lead(IV) acetates
Andrew Lethbridge Richard O. C. Norman and C. Barry Thomas
pg 2465; DOI:
10.1039/P19750002465
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Anodic syntheses. Part XVI. Oxidation of phenylenediacetic acids and benzylic ethers

pg 2471; DOI:
10.1039/P19750002471
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Syntheses of heterocyclic compounds. Part XXXI. Triazolium tetrafluoroborates from the cycloaddition of alkoxydiazenium salts to azines, hydrazones, and anils derived from aromatic aldehydes
Suchet S. Mathur and Hans Suschitzky
pg 2474; DOI:
10.1039/P19750002474
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Syntheses of heterocyclic compounds. Part XXXII. Intramolecular 1,3-dipolar cycloadditions of 2-allyloxy- and 2-prop-2-ynyloxy-aromatic aldehyde azines
Suchet S. Mathur and Hans Suschitzky
pg 2479; DOI:
10.1039/P19750002479
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Preparation and reactions of 2,5-dimethoxythiophen
John M. Barker Patrick R. Huddleston and Stephen W. Shutler
pg 2483; DOI:
10.1039/P19750002483
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Conversion of a catechol into a but-2-enolide
I. W. Sinclair and G. R. Proctor
pg 2485; DOI:
10.1039/P19750002485
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N-oxides and related compounds. Part L. Reactions of pyridinium and sulphonium ylides with pyrylium salts
Alan R. Katritzky S. Q. Abbas Rizvi and Jerzy W. Suwinski
pg 2489; DOI:
10.1039/P19750002489
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Phenol oxidation. Part IV. Synthesis and novel ring-opening of spirocyclic dienones related to the benzylisoquinoline alkaloid cularine
Anthony J. Birch Anthony H. Jackson Patrick V. R. Shannon and George W. Stewart
pg 2492; DOI:
10.1039/P19750002492
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Synthesis of 1,12b-didehydrolycoran (-anhydrodihydrocaranine) and 12b-lycoran (-lycoran)via photocyclisation of an enamide-ketone
Hideo Iida Sakae Aoyagi and Chihiro Kibayashi
pg 2502; DOI:
10.1039/P19750002502
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Absolute stereochemistry of the dihydroanthracene-cis- and trans-1,2-diols produced from anthracene by mammals and bacteria
M. Naseem Akhtar Derek R. Boyd Norris J. Thompson Masato Koreeda David T. Gibson Venkatanarayana Mahadevan and Donald M. Jerina
pg 2506; DOI:
10.1039/P19750002506
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A new synthesis of -amino-acids by the reaction of Grignard reagents with ethyl N-trichloroethylidenecarbamate
Choji Kashima Yoshiko Aoki and Yoshimori Omote
pg 2511; DOI:
10.1039/P19750002511
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Synthesis of 3-alkylidene-2,2,4,4-tetramethylthietan 1,1-dioxides, possible precursors of 2-methylenetrimethylene
R. J. Bushby
pg 2513; DOI:
10.1039/P19750002513
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Studies on the biosynthesis of -lactam antibiotics. Part II. Synthesis, and incorporation into penicillin G, of (2RS,2RS,3R,3R)-[3,3-3H2]cystine and (2RS,2RS,3S,3S)-[3,3-3H2]cystine
D. John Aberhart Lawrence J. Lin and John Yeou-Ruoh Chu
pg 2517; DOI:
10.1039/P19750002517
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Preparation of some fluoropalmitic acids and fluorination of brefeldin A
Brian E. Cross and Paul Hendley
pg 2523; DOI:
10.1039/P19750002523
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Studies related to penicillins and cephalosporins. Part IV. Synthesis of methyl 7-phthalimido-6,7-trans-DL-cepham-4-carboxylate
Mario D. Bachi and Karl J. Ross-Petersen
pg 2525; DOI:
10.1039/P19750002525
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Carotenoids and related compounds. Part XXXIII. Synthesis of dehydroflexixanthin and deoxyflexixanthin
Ruth E. Coman (née Holzel) and Basil C. L. Weedon
pg 2529; DOI:
10.1039/P19750002529
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